Facile Substitution of Bridging SO22– Ligands in Re12 Bioctahedral Cluster Complexes | Sciact - CRIS-system of Boreskov Institute of Catalysis

Facile Substitution of Bridging SO22– Ligands in Re12 Bioctahedral Cluster Complexes Full article

Journal

Inorganic Chemistry
ISSN: 0020-1669 , E-ISSN: 1520-510X

Output data

Year: 2017, Volume: 56, Number: 20, Pages: 12389-12400 Pages count : 12 DOI: 10.1021/acs.inorgchem.7b01889

Tags

ORDER REGULAR APPROXIMATION; RHENIUM CLUSTER; STRUCTURAL-CHARACTERIZATION; SOLUTION CHEMISTRY; SCREENING MODEL; SULFUR-DIOXIDE; CORE; SOLVATION; EXCHANGE; ENVIRONMENT

Authors

Gayfulin Yakov M. ¹ , Smolentsev Anton I. ^1,2 , Kozlova Svetlana G. ^1,2 , Novozhilov Igor N. ¹ , Plyusnin Pavel E. ^1,2 , Kompankov Nikolay B. ^1,2 , Mironov Yuri V. ^1,2

Affiliations

1	Nikolaev Institute of Inorganic Chemistry SB RAS
2	Novosibirsk State University

Selective substitution of μ-SO22– groups by either O2– or Se2– ions occurs upon heating the bioctahedral rhenium cluster complex K6[Re12CS14(μ-SO2)3(CN)6] in air atmosphere or in the presence of a Se source, respectively, manifesting the remarkable lability of SO22– ligands bound to a transition-metal cluster. A series of compounds based on the new mixed-ligand anions, [Re12CS14(μ-O)3(CN)6]6–, [Re12CS14(μ-Se)3(CN)6]6–, and [Re12CS14(μ-O)3(OH)6]6–, were isolated and their solid-state structures were elucidated by single-crystal X-ray diffraction analysis. Along with the previously reported μ-sulfide clusters, the new species constitute a series of rhenium anionic complexes with the common formula [Re12CS14(μ-Q)3L6]6– (Q = O, S, Se, L = CN–; Q = O, S, L = OH–), within which the total charge and number of cluster valence electrons (CVEs) are constant. The article presents insights into the mechanistic and synthetic aspects of the substitution process, and it comprehensively discusses the influence of inner ligand environment on the structure, spectroscopic characteristics, and electrochemical behavior of the novel compounds.

Gayfulin Y.M. , Smolentsev A.I. , Kozlova S.G. , Novozhilov I.N. , Plyusnin P.E. , Kompankov N.B. , Mironov Y.V.
Facile Substitution of Bridging SO22– Ligands in Re12 Bioctahedral Cluster Complexes
Inorganic Chemistry. 2017. V.56. N20. P.12389-12400. DOI: 10.1021/acs.inorgchem.7b01889 WOS Scopus РИНЦ ANCAN OpenAlex

Submitted:	Jul 25, 2017
Accepted:	Sep 22, 2017
Published online:	Sep 22, 2017
Published print:	Oct 16, 2017

Web of science:	WOS:000413279300036
Scopus:	2-s2.0-85031729965
Elibrary:	31085631
Chemical Abstracts:	2017:1535696
Chemical Abstracts (print):	167:440928
OpenAlex:	W2760697093

DB	Citing
Web of science	12
Scopus	15
OpenAlex	14