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Pyrolysis of a Mixture of Monosilane and Alkanes in a Compression Reactor to Produce Nanodispersed Silicon Carbide Full article

Journal Chemical Engineering Journal
ISSN: 1385-8947 , E-ISSN: 1873-3212
Output data Year: 2020, Volume: 381, Article number : 122642, Pages count : 5 DOI: 10.1016/j.cej.2019.122642
Tags Silicon carbide Silicon Synthesis from gas phase Pyrolysis Chemical compression reactor Semiconductive nanomaterials Cyclic flow pyrolysis method Nanoscale crystallites
Authors Ezdin B.S. 1 , Yatsenko D.A. 1,2 , Kalyada V.V. 1 , Ichshenko A.B. 1,2 , Zarvin A.E. 1 , Nikiforov A.A. 3 , Snytnikov P.V. 1,2
Affiliations
1 Novosibirsk State University
2 Boreskov Institute of Catalysis
3 Limited Liability Company “NICOM” st. Tereshkova 33, 630090 Novosibirsk, Russia

Funding (2)

1 Federal Agency for Scientific Organizations 0303-2016-0002
2 The Ministry of Education and Science of the Russian Federation 3.5920.2017/ИТР

Abstract: The method of producing of nano-dimensional silicon carbide by compressing in a cyclic chemical reactor is proposed. Pyrolysis is initiated in mixtures of monosilane and hydrocarbon with argon. The resulting product is examined by X-ray diffraction and electron microscopy. It is established that the powder contains crystallites of silicon carbide with an average size of 5–12 nm. It is shown that at certain ratios of precursor concentrations in argon, the formation of carbon nanoparticles and/or graphene coating on the surface of SiC particles is also possible. The method is technological and efficient, it can be used in the production of high purity silicon carbide nanopowders and other compounds.
Cite: Ezdin B.S. , Yatsenko D.A. , Kalyada V.V. , Ichshenko A.B. , Zarvin A.E. , Nikiforov A.A. , Snytnikov P.V.
Pyrolysis of a Mixture of Monosilane and Alkanes in a Compression Reactor to Produce Nanodispersed Silicon Carbide
Chemical Engineering Journal. 2020. V.381. 122642 :1-5. DOI: 10.1016/j.cej.2019.122642 WOS Scopus РИНЦ ANCAN OpenAlex
Dates:
Published online: Aug 28, 2019
Published print: Feb 1, 2020
Identifiers:
Web of science: WOS:000499066900089
Scopus: 2-s2.0-85071665853
Elibrary: 41626984
Chemical Abstracts: 2019:1911252
Chemical Abstracts (print): 171:450208
OpenAlex: W2971257853
Citing:
DB Citing
Scopus 13
Web of science 11
Elibrary 12
OpenAlex 18
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