Highly Active Carbon-Supported Ni Catalyst Prepared by Nitrate Decomposition with a Sacrificial Agent for the Hydrogen Oxidation Reaction in Alkaline Medium Full article
Journal |
Journal of Electroanalytical Chemistry
ISSN: 1572-6657 |
||||||||
---|---|---|---|---|---|---|---|---|---|
Output data | Year: 2019, Volume: 852, Article number : 113551, Pages count : 6 DOI: 10.1016/j.jelechem.2019.113551 | ||||||||
Tags | Alkaline solutions; Hydrogen oxidation reaction; Ketjenblack DJ-600; Lyophilization; Nickel | ||||||||
Authors |
|
||||||||
Affiliations |
|
Funding (2)
1 | French National Centre for Scientific Research | PRC1553 |
2 | Russian Foundation for Basic Research | 17-53-150008 |
Abstract:
Ketjenblack EC-600 JD supported Ni/C electrocatalysts with a nickel content of 50 and 60 wt% were prepared by impregnation with either Ni(OAc)2 or a mixture of Ni(OAc)2 and Ni(NO3)2 precursors, followed by freeze-drying and reduction with H2. XRD, TEM and cyclic voltammetry were applied for characterizing the catalysts. The use of Ni(OAc)2 as a sacrificial agent during decomposition of Ni(NO3)2 allows one to decrease significantly the size of nickel nanoparticles (from 37 to 12 nm) at a very high metal loading. Benefiting from the high dispersion and high specific activity, 60 % Ni/Ketjenblack EC-600 JD possesses remarkable mass activity (7 A∙g−1 Ni) in the hydrogen oxidation reaction in an alkaline electrolyte. © 2019 Elsevier B.V.
Cite:
Simonov P.A.
, Cherstiouk O.V.
, Kuznetsov A.N.
, Zaikovskii V.I.
, Kardash T.Y.
, Oshchepkov A.G.
, Bonnefont A.
, Savinova E.R.
Highly Active Carbon-Supported Ni Catalyst Prepared by Nitrate Decomposition with a Sacrificial Agent for the Hydrogen Oxidation Reaction in Alkaline Medium
Journal of Electroanalytical Chemistry. 2019. V.852. 113551 :1-6. DOI: 10.1016/j.jelechem.2019.113551 WOS Scopus РИНЦ ANCAN OpenAlex
Highly Active Carbon-Supported Ni Catalyst Prepared by Nitrate Decomposition with a Sacrificial Agent for the Hydrogen Oxidation Reaction in Alkaline Medium
Journal of Electroanalytical Chemistry. 2019. V.852. 113551 :1-6. DOI: 10.1016/j.jelechem.2019.113551 WOS Scopus РИНЦ ANCAN OpenAlex
Dates:
Submitted: | Jul 8, 2019 |
Accepted: | Oct 4, 2019 |
Published online: | Oct 7, 2019 |
Published print: | Nov 1, 2019 |
Identifiers:
Web of science: | WOS:000500386400019 |
Scopus: | 2-s2.0-85073095203 |
Elibrary: | 41684376 |
Chemical Abstracts: | 2019:1960783 |
Chemical Abstracts (print): | 171:463324 |
OpenAlex: | W2980285604 |