Boosting Hydrogen Production from Formic Acid over Pd Catalysts by Deposition of N-Containing Precursors on the Carbon Support | Sciact - CRIS-система Института катализа

Boosting Hydrogen Production from Formic Acid over Pd Catalysts by Deposition of N-Containing Precursors on the Carbon Support Научная публикация

Журнал

Energies
ISSN: 1996-1073

Вых. Данные

Год: 2019, Том: 12, Номер: 20, Номер статьи : 3885, Страниц : 13 DOI: 10.3390/en12203885

Ключевые слова

hydrogen production; formic acid decomposition; Pd/C; melamine; g-C3N4; bipyridine; phenanthroline; N-doped carbon

Авторы

Golub Fedor S. ^1,2 , Beloshapkin Sergey ³ , Gusel’nikov Artem V. ⁴ , Bolotov Vasiliy A. ¹ , Parmon Valentin N. ^1,2 , Bulushev Dmitri A. ^1,2

Организации

1	Laboratory of Catalytic Methods of Solar Energy Transformation, Boreskov Institute of Catalysis, SB RAS, 630090 Novosibirsk, Russia
2	Department of Natural Sciences, Novosibirsk State University, 630090 Novosibirsk, Russia
3	Bernal Institute, University of Limerick, Limerick V94 T9PX, Ireland
4	Laboratory of Physico-Chemistry of Nanomaterials, Nikolaev Institute of Inorganic Chemistry, SB RAS, 630090 Novosibirsk, Russia

Информация о финансировании (1)

Российский научный фонд

17-73-30032

Formic acid is a promising liquid organic hydrogen carrier (LOHC) since it has relatively high hydrogen content (4.4 wt%), low inflammability, low toxicity and can be obtained from biomass or from CO2. The aim of the present research was the creation of efficient 1 wt% Pd catalysts supported on mesoporous graphitic carbon (Sibunit) for the hydrogen production from gas-phase formic acid. For this purpose, the carbon support was modified by pyrolysis of deposited precursors containing pyridinic nitrogen such as melamine (Mel), 2,2′-bipyridine (Bpy) or 1,10-phenanthroline (Phen) at 673 K. The following activity trend of the catalysts Pd/Mel/C > Pd/C ~ Pd/Bpy/C > Pd/Phen/C was obtained. The activity of the Pd/Mel/C catalyst was by a factor of 4 higher than the activity of the Pd/C catalyst at about 373 K and the apparent activation energy was significantly lower than those for the other catalysts (32 vs. 42–46 kJ/mol). The high activity of the melaminebased samples was explained by a high dispersion of Pd nanoparticles (~2 nm, HRTEM) and their strong electron-deficient character (XPS) provided by interaction of Pd with pyridinic nitrogen species of the support. The presented results can be used for the development of supported Pd catalysts for hydrogen production from different liquid organic hydrogen carriers.

Golub F.S. , Beloshapkin S. , Gusel’nikov A.V. , Bolotov V.A. , Parmon V.N. , Bulushev D.A.
Boosting Hydrogen Production from Formic Acid over Pd Catalysts by Deposition of N-Containing Precursors on the Carbon Support

Energies. 2019. V.12. N20. 3885 :1-13. DOI: 10.3390/en12203885 WOS Scopus РИНЦ CAPlus OpenAlex

Полный текст от издателя

Поступила в редакцию:	18 сент. 2019 г.
Принята к публикации:	11 окт. 2019 г.
Опубликована online:	14 окт. 2019 г.

Web of science:	WOS:000498391700081
Scopus:	2-s2.0-85074969213
РИНЦ:	41710019
Chemical Abstracts:	2020:681629
OpenAlex:	W2979860771

БД	Цитирований
Scopus	33
Web of science	22
РИНЦ	28
OpenAlex	35