Chromatographic Properties and Polarity Evaluation of Poly(1-Trimethylsilyl-1-Propyne) and Poly(-1-Phenyl-1-Propyne) Full article
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Journal of Analytical Chemistry
ISSN: 1061-9348 , E-ISSN: 1608-3199 |
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| Output data | Year: 2010, Volume: 65, Number: 10, Pages: 1014-1020 Pages count : 7 DOI: 10.1134/S1061934810100059 | ||
| Tags | POLYMERIZATION; HALIDES | ||
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Abstract:
The chromatographic properties of poly(1-trimethylsilyl-1-propyne) (PTMSP) and poly(1-phenyl-1-propyne) (PPP) were studied by gas chromatography using packed columns. The selectivity and efficiency of columns packed with PTMSP and PPP were compared to the data obtained for columns with other known adsorbents and stationary phases. The McReynolds and Rohrschneider constants, on the basis of which the polarity of the new phases was evaluated, were calculated. The results of the investigation of chromatographic properties allow PTMSP to be brought in line with the polymeric adsorbents Porapak Q, Porapak QS, and Chromosorb 106, while PPP, with the methyphenylsilicon phases SE-52 and OV-3.
Cite:
Yakovleva E.Y.
, Belotserkovskaya V.Y.
Chromatographic Properties and Polarity Evaluation of Poly(1-Trimethylsilyl-1-Propyne) and Poly(-1-Phenyl-1-Propyne)
Journal of Analytical Chemistry. 2010. V.65. N10. P.1014-1020. DOI: 10.1134/S1061934810100059 WOS Scopus РИНЦ ANCAN OpenAlex
Chromatographic Properties and Polarity Evaluation of Poly(1-Trimethylsilyl-1-Propyne) and Poly(-1-Phenyl-1-Propyne)
Journal of Analytical Chemistry. 2010. V.65. N10. P.1014-1020. DOI: 10.1134/S1061934810100059 WOS Scopus РИНЦ ANCAN OpenAlex
Original:
Яковлева Е.Ю.
, Белоцерковская В.Ю.
Хроматографические свойства и оценка полярности поли(1-триметилсилил-1-пропина) и поли(1-фенил-1-пропина)
Журнал аналитической химии. 2010. Т.65. №10. С.1039-1045. РИНЦ
Хроматографические свойства и оценка полярности поли(1-триметилсилил-1-пропина) и поли(1-фенил-1-пропина)
Журнал аналитической химии. 2010. Т.65. №10. С.1039-1045. РИНЦ
Dates:
| Submitted: | Jun 29, 2009 |
| Accepted: | Dec 28, 2009 |
| Published print: | Oct 1, 2010 |
| Published online: | Oct 6, 2010 |
Identifiers:
| Web of science: | WOS:000282514100005 |
| Scopus: | 2-s2.0-78049376560 |
| Elibrary: | 16720243 |
| Chemical Abstracts: | 2010:1238769 |
| Chemical Abstracts (print): | 153:658292 |
| OpenAlex: | W2075901992 |