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Effect of Nitrogen Bases on the Structure of Primary Asphaltene Clusters and Dynamics of Aggregation of Heavy Oil Fractions Full article

Journal Petroleum Chemistry
ISSN: 0965-5441 , E-ISSN: 1531-8532
Output data Year: 2019, Volume: 59, Number: 11, Pages: 1195-1200 Pages count : 6 DOI: 10.1134/S0965544119110100
Tags asphaltenes; nitrogen-containing petroleum bases; small-angle X-ray scattering; supramolecular structure
Authors Larichev Yu.V. 1,2 , Kovalenko E.Yu. 3 , Mart’yanov O.N. 1,2
Affiliations
1 Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences, Novosibirsk, 630090, Russian Federation
2 Novosibirsk National Research State University, Novosibirsk, 630090, Russian Federation
3 Institute of Petroleum Chemistry, Siberian Branch, Russian Academy of Sciences, Tomsk, 634055, Russian Federation

Funding (1)

1 Russian Science Foundation 15-19-00119

Abstract: Using the method of small-angle X-ray scattering (SAXS), the effect of nitrogen-containing compounds on the structure of primary asphaltene clusters and changes in their structure and size characteristics has been studied. It has been shown that the addition of nitrogen bases leads to a partial degradation of the primary aggregates of asphaltenes and the appearance of a larger number of disordered “non-compact” fragments in the solution, thereby altering the dynamics of the entire aggregation process. Nitrogen bases also provoke a change in the type of packing of the primary particles of asphaltenes, facilitating the formation of a looser secondary structure of asphaltene aggregates. © 2019, Pleiades Publishing, Ltd.
Cite: Larichev Y.V. , Kovalenko E.Y. , Mart’yanov O.N.
Effect of Nitrogen Bases on the Structure of Primary Asphaltene Clusters and Dynamics of Aggregation of Heavy Oil Fractions
Petroleum Chemistry. 2019. V.59. N11. P.1195-1200. DOI: 10.1134/S0965544119110100 WOS Scopus РИНЦ AN OpenAlex
Original: Ларичев Ю.В. , Коваленко Е.Ю. , Мартьянов О.Н.
Влияние азотсодержащих оснований на строение первичных кластеров асфальтенов и динамику процесса агрегации тяжелых фракций нефти
Нефтехимия. 2019. Т.59. №6. С.638-644. DOI: 10.1134/S0028242119060108 РИНЦ OpenAlex
Dates:
Submitted: Apr 4, 2019
Accepted: Jul 4, 2019
Published print: Nov 1, 2019
Published online: Nov 14, 2019
Identifiers:
Web of science: WOS:000496562300004
Scopus: 2-s2.0-85075170377
Elibrary: 41820435
Chemical Abstracts: 2019:2159681
OpenAlex: W2983738704
Citing:
DB Citing
Scopus 9
Web of science 9
Elibrary 9
OpenAlex 5
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