Structure and Properties of Tripyridine Nitrosocomplexes of Ruthenium: mer-[Ru(NO)Py3Cl(OH)]Cl·1.5H2O and mer-[Ru(NO)Py3Cl(H2O)]Cl2·2H2O·0.5HCl Full article
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Journal of Structural Chemistry
ISSN: 0022-4766 , E-ISSN: 1573-8779 |
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| Output data | Year: 2014, Volume: 55, Number: 4, Pages: 682-690 Pages count : 9 DOI: 10.1134/s0022476614040131 | ||||
| Tags | amine complexes; IR spectroscopy; nitrosocomplexes; NMR; pyridine; ruthenium; thermal analysis; X-ray crystallography | ||||
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Abstract:
The reaction of K2[Ru(NO)Cl5] with pyridine in aqueous ethanol at pH ∼ 7–8 affords a nitrosoruthenium hydroxocomplex mer-[Ru(NO)Py3Cl(OH)]Cl·1.5H2O (I) (yield ∼55%). Treatment of hydroxocomplex I with hydrochloric acid at room temperature gives the aqua complex mer-[Ru(NO)Py3Cl(H2O)]Cl2·2H2O·0.5HCl (II). The structures of the compounds are determined by X-ray crystallography: I, space group P21/n, a = 9.2292(4) Å, b = 11.7781(4) Å, c = 17.4915(7) Å, β = 90.9560(10)°, R = 4.84%; II, space group P-1, a = 7.3528(9) Å, b = 11.5793(11) Å, c = 13.6961(16) Å, α = 84.558(3)°, β = 87.668(4)°, γ = 74.146(4)°, R = 6.22%. Compounds I and II are characterized by powder XRD, 1H and 13C NMR, and IR spectroscopy. The thermal decomposition of compound II in the inert atmosphere is examined by thermal analysis
Cite:
Makhinya A.N.
, Il’in M.A.
, Baidina I.A.
, Plyusnin P.E.
, Gallyamov M.R.
Structure and Properties of Tripyridine Nitrosocomplexes of Ruthenium: mer-[Ru(NO)Py3Cl(OH)]Cl·1.5H2O and mer-[Ru(NO)Py3Cl(H2O)]Cl2·2H2O·0.5HCl
Journal of Structural Chemistry. 2014. V.55. N4. P.682-690. DOI: 10.1134/s0022476614040131 WOS Scopus РИНЦ ANCAN OpenAlex
Structure and Properties of Tripyridine Nitrosocomplexes of Ruthenium: mer-[Ru(NO)Py3Cl(OH)]Cl·1.5H2O and mer-[Ru(NO)Py3Cl(H2O)]Cl2·2H2O·0.5HCl
Journal of Structural Chemistry. 2014. V.55. N4. P.682-690. DOI: 10.1134/s0022476614040131 WOS Scopus РИНЦ ANCAN OpenAlex
Original:
Махиня А.Н.
, Ильин М.А.
, Байдина И.А.
, Плюснин П.Е.
, Галлямов М.Р.
Строение и свойства нитрозокомплексов рутения трипиридинового ряда ос-[Ru(NO)Py3Cl(OH)]Cl · 1,5H2O и ос-[Ru(NO)Py3Cl(H2O)]Cl2 · 2H2O · 0,5HCl
Журнал структурной химии. 2014. Т.55. №4. С.716-724.
Строение и свойства нитрозокомплексов рутения трипиридинового ряда ос-[Ru(NO)Py3Cl(OH)]Cl · 1,5H2O и ос-[Ru(NO)Py3Cl(H2O)]Cl2 · 2H2O · 0,5HCl
Журнал структурной химии. 2014. Т.55. №4. С.716-724.
Dates:
| Submitted: | Jul 3, 2013 |
| Published print: | Jul 1, 2014 |
| Published online: | Sep 21, 2014 |
Identifiers:
| Web of science: | WOS:000342415000013 |
| Scopus: | 2-s2.0-84919340785 |
| Elibrary: | 24019457 |
| Chemical Abstracts: | 2014:1582540 |
| Chemical Abstracts (print): | 162:29248 |
| OpenAlex: | W1964054489 |