Design of Anode Materials for IT SOFC: Effect of Complex Oxide Promoters and Pt Group Metals on Activity and Stability in Methane Steam Reforming of Ni/YSZ (ScSZ) Cermets Full article
| Conference |
5th International Conference on Fuel Cell Science, Engineering and Technology 18-20 Jun 2007 , New York |
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| Journal |
Journal of Fuel Cell Science and Technology
ISSN: 1550-624X , E-ISSN: 1551-6989 |
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| Output data | Year: 2010, Volume: 7, Number: 1, Article number : 011005, Pages count : 6 DOI: 10.1115/1.3117255 | ||||||||||
| Tags | CH4 TPR, Lattice oxygen reactivity, Methane steam reforming, Ni/8YSZ and Ni/ScCeSZ, Pd, Perovskite and fluoritelike oxide promoters, Pt, Ru, SOFC composite anodes | ||||||||||
| Authors |
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| Affiliations |
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Funding (4)
| 1 | North Atlantic Treaty Organization | SfP-980878 |
| 2 | Siberian Branch of the Russian Academy of Sciences | 95 |
| 3 | International Association for the Promotion of Co-operation with Scientists from the New Independent States of the Former Soviet Union | YSF 06-1000014-5773 |
| 4 | European Commission | 20089 FP6-2004-ENERGY-3 SOFC600 |
Abstract:
Ni/YSZ or Ni/ScCeSZ cermets were promoted by up to 10 wt % of fluoritelike (Pr–Ce–Zr–О, La–Ce–Zr–О, and Ce–Zr–О) or perovskitelike (La–Pr–Mn–Cr–O) oxides and small (up to 1.4 wt %) amounts of Pt group metals (Pd, Pt, or Ru). Reactivity of samples, their lattice oxygen mobility, and their ability to activate methane were characterized by temperature-programed reduction by CH4. The catalytic properties of these samples in methane steam reforming were studied at 500–850°C and short contact times (10 ms) in feeds with 8 mol % of CH4 and steam/methane ratio of 1:3. Oxide promoters ensure stable performance of cermets in stoichiometric feeds at T>650°C by suppressing carbon deposition. Copromotion with precious metals enhances performance in the intermediate temperature (450–600°C) range due to more efficient activation of methane. Factors determining specificity of these cermet materials’ performance (chemical composition, microstructure, oxygen mobility in oxides, interaction between components, and reaction media effect) are considered. The most promising systems for practical application are Pt/Pr–Ce–Zr–O/Ni/YSZ and Ru/La–Pr–Mn–Cr–O/Ni/YSZ cermets demonstrating a high performance in the intermediate temperature range under broad variation in steam/CH4 ratio
Cite:
Sadykov V.A.
, Mezentseva N.V.
, Bunina R.V.
, Alikina G.M.
, Lukashevich A.I.
, Zaikovskii V.I.
, Bobrenok O.F.
, Irvine J.
, Vasylyev O.D.
, Smirnova A.L.
Design of Anode Materials for IT SOFC: Effect of Complex Oxide Promoters and Pt Group Metals on Activity and Stability in Methane Steam Reforming of Ni/YSZ (ScSZ) Cermets
Journal of Fuel Cell Science and Technology. 2010. V.7. N1. 011005 :1-6. DOI: 10.1115/1.3117255 WOS Scopus РИНЦ ANCAN OpenAlex
Design of Anode Materials for IT SOFC: Effect of Complex Oxide Promoters and Pt Group Metals on Activity and Stability in Methane Steam Reforming of Ni/YSZ (ScSZ) Cermets
Journal of Fuel Cell Science and Technology. 2010. V.7. N1. 011005 :1-6. DOI: 10.1115/1.3117255 WOS Scopus РИНЦ ANCAN OpenAlex
Dates:
| Published online: | Oct 6, 2009 |
| Published print: | Feb 1, 2010 |
Identifiers:
| Web of science: | WOS:000271667600005 |
| Scopus: | 2-s2.0-77955299508 |
| Elibrary: | 15327127 |
| Chemical Abstracts: | 2010:533887 |
| Chemical Abstracts (print): | 154:365059 |
| OpenAlex: | W2047401872 |