Structure, Synthesis, and Thermal Properties of trans-[Ru(NO)(NH3)4(SO4)]NO3·H2O Full article
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Journal of Structural Chemistry
ISSN: 0022-4766 , E-ISSN: 1573-8779 |
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| Output data | Year: 2014, Volume: 55, Number: 2, Pages: 311-318 Pages count : 8 DOI: 10.1134/s0022476614020188 | ||||
| Tags | amino complexes; nitroso complexes; ruthenium; single crystal X-ray diffraction analysis; sulfato complexes; synthesis; thermal analysis | ||||
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Abstract:
In treatment of trans-[Ru(NO)(NH3)4(OH)]Cl2 with concentrated sulfuric acid on heating trans-
[Ru(NO)(NH3)4(SO4)](HSO4)⋅H2O (I) is obtained with a yield close to quantitative. In the interaction of the
saturated solution of I with a saturated NaNO3 solution a trans-[Ru(NO)(NH3)4(SO4)]NO3⋅H2O (II)
precipitate forms whose structure is determined by single crystal XRD: space group Р212121, a = 6.8406(3) Å,
b = 12.6581(5) Å, c = 13.3291(5) Å. A monodentately coordinated sulfate ion is in the trans-position to the
nitroso group. Compound II is characterized by IR spectroscopy, powder XRD, and diffuse reflectance
spectroscopy. The process of its thermolysis is studied; by differential scanning calorimetry the thermal
effect of the dehydration reaction occurring on heating to 120°C (ΔH = 58.9 ± 1.5 kJ/mol) is estimated. The
final product of the thermolysis of II is a mixture of Ru and RuO2.
Cite:
Makhinya A.N.
, Il’in M.A.
, Baidina I.A.
, Plyusnin P.E.
, Alferova N.I.
, Pishchur D.P.
Structure, Synthesis, and Thermal Properties of trans-[Ru(NO)(NH3)4(SO4)]NO3·H2O
Journal of Structural Chemistry. 2014. V.55. N2. P.311-318. DOI: 10.1134/s0022476614020188 WOS Scopus РИНЦ ANCAN OpenAlex
Structure, Synthesis, and Thermal Properties of trans-[Ru(NO)(NH3)4(SO4)]NO3·H2O
Journal of Structural Chemistry. 2014. V.55. N2. P.311-318. DOI: 10.1134/s0022476614020188 WOS Scopus РИНЦ ANCAN OpenAlex
Original:
Махиня А.Н.
, Ильин М.А.
, Байдина И.А.
, Плюснин П.Е.
, Алферова Н.И.
, Пищур Д.П.
Строение, синтез и термические свойства транс-[Ru(NO)(NH3)4(SO4)]NO 3×H2O
Журнал структурной химии. 2014. Т.55. №2. С.331-338. RSCI РИНЦ
Строение, синтез и термические свойства транс-[Ru(NO)(NH3)4(SO4)]NO 3×H2O
Журнал структурной химии. 2014. Т.55. №2. С.331-338. RSCI РИНЦ
Dates:
| Submitted: | Feb 19, 2013 |
| Published print: | Mar 1, 2014 |
| Published online: | May 25, 2014 |
Identifiers:
| Web of science: | WOS:000336388200018 |
| Scopus: | 2-s2.0-84902107757 |
| Elibrary: | 24053902 |
| Chemical Abstracts: | 2014:853425 |
| Chemical Abstracts (print): | 161:709666 |
| OpenAlex: | W2008710435 |