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Modification of Sulfide-Based Photocatalyst with Zinc- and Nickel-Containing Compounds: Correlation Between Photocatalytic Activity and Photoelectrochemical Parameters Full article

Journal Renewable Energy
ISSN: 0960-1481 , E-ISSN: 1879-0682
Output data Year: 2020, Volume: 151, Pages: 286-294 Pages count : 9 DOI: 10.1016/j.renene.2019.11.030
Tags Cd0.3Zn0.7S, Photocatalytic hydrogen production, Na2S/Na2SO3, Photoelectrochemistry, Visible light
Authors Markovskaya Dina V. 1,2 , Gribov Evgenii N. 1,2 , Kozlova Ekaterina A. 1,2 , Kozlov Denis V. 1,2 , Parmon Valentin N. 1,2
Affiliations
1 Boreskov Institute of Catalysis SB RAS, Lavrentieva Ave., 5, Novosibirsk, 630090, Russia
2 Novosibirsk State University, Pirogova Str., 2, Novosibirsk, 630090, Russia

Funding (1)

1 Federal Agency for Scientific Organizations 0303-2016-0016

Abstract: The photoanodes made of Cd0.3Zn0.7S and FTO were prepared and modified by Ni(OH)2, Zn(OH)2, and NiS as co-catalysts. The amounts of the co-catalysts were the same as those in the most active photocatalysts tested earlier in photocatalytic hydrogen production. The obtained electrodes were studied by X-ray diffraction and photoelectron spectroscopy, scanning and transmission electron microscopy, cyclic voltammetry, and electrochemical impedance spectroscopy. The modification of the photoelectrode surface led to the growth of short-circuit current density, power conversion efficiency and photogenerated charge carriers lifetime, while open-circuit voltage, fill factor, and resistivity fell. The changes in the photocatalytic activity and the photoelectrochemical properties of the tested samples were found to correlate with each other, which indicated the same origin of the studied phenomenon. © 2019 Elsevier Ltd
Cite: Markovskaya D.V. , Gribov E.N. , Kozlova E.A. , Kozlov D.V. , Parmon V.N.
Modification of Sulfide-Based Photocatalyst with Zinc- and Nickel-Containing Compounds: Correlation Between Photocatalytic Activity and Photoelectrochemical Parameters
Renewable Energy. 2020. V.151. P.286-294. DOI: 10.1016/j.renene.2019.11.030 WOS Scopus РИНЦ ANCAN OpenAlex
Dates:
Submitted: Apr 5, 2019
Accepted: Nov 8, 2019
Published online: Nov 11, 2019
Published print: May 1, 2020
Identifiers:
Web of science: WOS:000521120700024
Scopus: 2-s2.0-85075339925
Elibrary: 41811267
Chemical Abstracts: 2019:2199289
Chemical Abstracts (print): 172:286438
OpenAlex: W2987971077
Citing:
DB Citing
Scopus 16
Elibrary 13
Web of science 12
OpenAlex 15
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