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Kinetics of Reaction on a Single Catalytic Particle in a Fluidic Nanochannel Научная публикация

Журнал Catalysis Letters
ISSN: 1011-372X , E-ISSN: 1572-879X
Вых. Данные Год: 2020, Том: 150, Номер: 6, Страницы: 1749–1756 Страниц : 8 DOI: 10.1007/s10562-019-03082-1
Ключевые слова Dirichlet and Danckwerts boundary conditions; Fluidic nanochannel; Reaction kinetics; Single catalytic nanoparticle
Авторы Zhdanov Vladimir P. 1,2
Организации
1 Section of Chemical Physics, Department of Physics, Chalmers University of Technology, Göteborg, Sweden
2 Boreskov Institute of Catalysis, Russian Academy of Sciences, Novosibirsk, Russia

Информация о финансировании (2)

1 Федеральное агентство научных организаций России 0303-2016-0001
2 Chalmers University of Technology

Реферат: One of the frontiers in heterogeneous catalysis is focused on reactions occurring on single catalytic nanoparticles. In this context, a reaction taking place on a single nanoparticle in a fluidic nanochannel is herein described by using the equation similar to that employed for a plug-flow reactor with dispersion. In the literature, one can find various boundary conditions for this equation. In the practically interesting case of a relatively long channel, the Dirichlet boundary conditions are shown to be valid. The corresponding analytical and numerical results illustrate the specifics of the profiles of the reactant concentration along the channel and the dependence of the reaction rate on the parameters. For comparison, the Danckwerts boundary conditions were used as well. Graphic Abstract: [Figure not available: see fulltext.] © 2019, The Author(s).
Библиографическая ссылка: Zhdanov V.P.
Kinetics of Reaction on a Single Catalytic Particle in a Fluidic Nanochannel
Catalysis Letters. 2020. V.150. N6. P.1749–1756. DOI: 10.1007/s10562-019-03082-1 WOS Scopus РИНЦ CAPlus OpenAlex
Файлы: Полный текст от издателя
Даты:
Поступила в редакцию: 22 окт. 2019 г.
Принята к публикации: 13 дек. 2019 г.
Опубликована online: 27 дек. 2019 г.
Опубликована в печати: 1 июн. 2020 г.
Идентификаторы БД:
Web of science: WOS:000504591300001
Scopus: 2-s2.0-85077362317
РИНЦ: 43224896
Chemical Abstracts: 2020:25934
OpenAlex: W2997357828
Цитирование в БД:
БД Цитирований
Scopus 1
Web of science 1
РИНЦ 1
OpenAlex 1
Альметрики: