Study of the Structure of Mixed Zr-Y-O and Zr-Y-Mg-O Oxides by XRD and XAFS Methods Full article
Conference |
VIII International Conference "Deformation and fracture of materials and nanomaterials" 19-22 Nov 2019 , Москва |
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Journal |
Journal of Physics: Conference Series
ISSN: 1742-6588 , E-ISSN: 1742-6596 |
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Output data | Year: 2020, Volume: 1431, Number: 1, Article number : 012057, Pages count : 7 DOI: 10.1088/1742-6596/1431/1/012057 | ||||
Tags | Deformation; Fluorspar; Fracture mechanics; Magnesium compounds; Nanostructured materials; X ray diffraction; Yttrium | ||||
Authors |
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Affiliations |
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Funding (1)
1 | Russian Foundation for Basic Research | 19-03-00530 (АААА-А19-119022890079-0) |
Abstract:
A comparative study was carried out of the structure of samples of zirconium oxides modified by yttrium and magnesium, synthesized by coprecipitation and calcined during 10 days at a temperature of 1250 °C. Refinement of the structure of the samples according to diffraction data within the framework of the fluorite type, gives high uncertainty factors, regardless of composition, and variation of structural parameters does not reduce their value. EXAFS analysis of the local structure of the samples revealed separate clusters consisting only of yttrium and oxygen ions in the structure of both samples. It has been suggested that the presence of these clusters prevents refinement of structures using the model of statistical solid solution with a fluorite structure.
Cite:
Moroz E.M.
, Zyuzin D.A.
, Kriventsov V.V.
, Udovsky A.L.
, Saenko I.S.
Study of the Structure of Mixed Zr-Y-O and Zr-Y-Mg-O Oxides by XRD and XAFS Methods
Journal of Physics: Conference Series. 2020.
V.1431. N1. 012057
:1-7. DOI: 10.1088/1742-6596/1431/1/012057
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Study of the Structure of Mixed Zr-Y-O and Zr-Y-Mg-O Oxides by XRD and XAFS Methods
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Full text from publisher
Dates:
Published print: | Jan 7, 2020 |
Published online: | Jan 7, 2020 |
Identifiers:
Scopus: | 2-s2.0-85079042888 |
Elibrary: | 43246541 |
Chemical Abstracts: | 2020:1919839 |
OpenAlex: | W2998566156 |