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Effect of Li, Na and K Modification of Alumina on its Physical and Chemical Properties and Water Adsorption Ability Full article

Journal Materials
ISSN: 1996-1944
Output data Year: 2019, Volume: 12, Number: 24, Article number : 4212, Pages count : 13 DOI: 10.3390/ma12244212
Tags aluminium oxide material; material modification with ions; water adsorption; dynamic adsorption
Authors Reshetnikov Sergey 1 , Kurzina Irina 2 , Livanova Alesia 2 , Meshcheryakov Eugene 2 , Isupova Lyubov 1
Affiliations
1 Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences, Novosibirsk 630090, Russia
2 Faculty of Chemistry, National Research Tomsk State University, Tomsk 634050, Russia

Funding (1)

1 The Ministry of Education and Science of the Russian Federation 8.2.10.2018

Abstract: The effect of alkali metal (Li, Na, K) incorporation on the morphology and water vapor uptake properties of mesoporous Al2O3 has been studied. The modification of the raw material, pseudoboehmite, represented a mixture of low-temperature phases (γ + η + χ)-Al2O3, and has been done at low-temperature that does not change the phase ratio. A decrease in specific surface values and an average pores size increase were observed as a result of the introduction of metal cations by impregnation and subsequent thermal treatment. The influence of the content of the modifying metal on the adsorption ability of the obtained samples in relation to water vapours has been studied. It has been established that alkaline modification Al2O3 with the lithium cations did not result in adsorption ability improvement, whereas samples that were modified with sodium or potassium in the amount of 1.2 weight % and 2.6 weight %, respectively, possess a higher equilibrium capacity (by ~40%), as compared to that of the initial sample (Al2O3), and a sufficiently high adsorption rate.
Cite: Reshetnikov S. , Kurzina I. , Livanova A. , Meshcheryakov E. , Isupova L.
Effect of Li, Na and K Modification of Alumina on its Physical and Chemical Properties and Water Adsorption Ability
Materials. 2019. V.12. N24. 4212 :1-13. DOI: 10.3390/ma12244212 WOS Scopus РИНЦ AN PMID OpenAlex
Files: Full text from publisher
Dates:
Submitted: Nov 26, 2019
Published print: Dec 2, 2019
Accepted: Dec 11, 2019
Published online: Dec 15, 2019
Identifiers:
Web of science: WOS:000507308200190
Scopus: 2-s2.0-85078883859
Elibrary: 43252125
Chemical Abstracts: 2020:911147
PMID: 31847442
OpenAlex: W2995743265
Citing:
DB Citing
Web of science 11
Scopus 13
Elibrary 11
OpenAlex 14
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