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Transformation of Petroleum Asphaltenes in Supercritical Water Full article

Journal The Journal of Supercritical Fluids
ISSN: 0896-8446 , E-ISSN: 1872-8162
Output data Year: 2010, Volume: 55, Number: 1, Pages: 217-222 Pages count : 6 DOI: 10.1016/j.supflu.2010.08.009
Tags Asphaltenes, Cracking, Dealkylation, Supercritical water
Authors Kozhevnikov I.V. 1,2 , Nuzhdin A.L. 1 , Martyanov O.N. 1,2
Affiliations
1 Boreskov Institute of Catalysis, Siberian Branch of the Russian Academy of Sciences
2 Department of Natural Sciences, Novosibirsk State University

Funding (1)

1 Siberian Branch of the Russian Academy of Sciences 118

Abstract: The transformation of petroleum asphaltenes in supercritical water was studied. The experiments were performed in autoclave at temperature 380 °C and pressure 226 atm with stirring for 3 h, medium density was about 0.33 g/cm3. The reaction resulted in the formation of gas products, about 4.3%, and an insoluble residue (coke) with about 48.6% yield. The remaining products were separated into fractions by consecutive dissolution in hexane (30.0%), benzene (10.6%), and chloroform (5.7%). The properties of the obtained products were studied with FT-IR spectrometry and 1H NMR spectroscopy. The method of simulated distillation was used to demonstrate that the fractional composition of the hexane-soluble part of the products is close to the fractional composition of a mixture of the diesel fraction and vacuum gas oil of the corresponding oil in 1:1 ratio. The obtained data support the conclusion that asphaltene cracking proceeds in SCW, with most probable main processes being dealkylation of substituents in the aromatic fragments of molecules and aromatization. This leads to formation of gaseous products and hexane-soluble fraction consisting of lighter aliphatic and aromatic compounds, as well as carbonized solid residue.
Cite: Kozhevnikov I.V. , Nuzhdin A.L. , Martyanov O.N.
Transformation of Petroleum Asphaltenes in Supercritical Water
The Journal of Supercritical Fluids. 2010. V.55. N1. P.217-222. DOI: 10.1016/j.supflu.2010.08.009 WOS Scopus РИНЦ ANCAN OpenAlex
Dates:
Submitted: Jun 3, 2010
Accepted: Aug 23, 2010
Published online: Aug 30, 2010
Published print: Nov 1, 2010
Identifiers:
Web of science: WOS:000284815300029
Scopus: 2-s2.0-78049252231
Elibrary: 16667932
Chemical Abstracts: 2010:1339997
Chemical Abstracts (print): 155:186519
OpenAlex: W1972846558
Citing:
DB Citing
Web of science 101
Scopus 116
Elibrary 120
OpenAlex 105
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