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Effects of the Modification of Reforming Alumina–Platinum Catalysts with Zirconium Full article

Journal Kinetics and Catalysis
ISSN: 0023-1584 , E-ISSN: 1608-3210
Output data Year: 2010, Volume: 51, Number: 1, Pages: 81-87 Pages count : 7 DOI: 10.1134/S0023158410010143
Tags Boehmite; Zirconium Sulfate; Zirconium Content; Zirconium Hydroxide; Dehydrocyclization
Authors Udras I.E. 1 , Zatolokina E.V. 1 , Paukshtis E.A. 2 , Belyi A.S. 1
Affiliations
1 Institute of Hydrocarbon Processing, Siberian Branch, Russian Academy of Sciences
2 Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences

Abstract: The effects of the modification of supported platinum as a constituent of reforming Pt/Al2O3 and Pt-Re/Al2O3 catalysts by introducing zirconium, which was obtained from various starting compounds, into the composition of the support were studied. These effects were most pronounced if difficult-to-hydrolyze compounds served as a source of zirconium. It was found that zirconium affected the metal-support interaction strength, which is responsible for the formation of the most strongly adsorbed hydrogen species (over the temperature range of 300–500°C). This suggests a change in the electronic state of platinum under the action of zirconium. Platinum sites became more regular; as a result of this, the reaction rate parameters of heptane conversion changed.
Cite: Udras I.E. , Zatolokina E.V. , Paukshtis E.A. , Belyi A.S.
Effects of the Modification of Reforming Alumina–Platinum Catalysts with Zirconium
Kinetics and Catalysis. 2010. V.51. N1. P.81-87. DOI: 10.1134/S0023158410010143 WOS Scopus РИНЦ ANCAN OpenAlex
Original: Удрас И.Е. , Затолокина Е.В. , Паукштис Е.А. , Белый А.С.
Исследование эффектов модифицирования цирконием алюмоплатиновых катализаторов риформинга
Кинетика и катализ. 2010. Т.51. №1. С.88-94. РИНЦ
Dates:
Submitted: Jul 8, 2008
Published print: Feb 1, 2010
Published online: Mar 17, 2010
Identifiers:
Web of science: WOS:000275703300014
Scopus: 2-s2.0-77952019737
Elibrary: 15326417
Chemical Abstracts: 2010:327003
Chemical Abstracts (print): 154:489907
OpenAlex: W2070750208
Citing:
DB Citing
Web of science 9
Scopus 9
Elibrary 27
OpenAlex 11
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