Green Stereoselective Oxidations, Catalyzed by Bioinspired bis-Amine-bis-Pyridine Manganese Complexes | Sciact - CRIS-система Института катализа

Green Stereoselective Oxidations, Catalyzed by Bioinspired bis-Amine-bis-Pyridine Manganese Complexes Тезисы доклада

Конференция

7th Asian Conference on Coordination Chemistry
15-18 окт. 2019 , Kuala Lumpur

Сборник

7th Asian Conference on Coordination Chemistry.Abstract Book
Сборник, 2019. 340 c.

Вых. Данные

Год: 2019, Страницы: 26 Страниц : 1

Ключевые слова

asymmetric; epoxidation; C-H oxidation; manganese; hydrogen peroxide

Авторы

Ottenbacher Roman V. ^1,2 , Bryliakova Anna A. ² , Talsi Evgenii P. ^1,2 , Bryliakov Konstantin P. ^1,2

Организации

1	Novosibirsk State University, Pirogova 2, Novosibirsk 630090, Russia
2	Boreskov Institute of Catalysis, Lavrentieva 5, Novosibirsk 630090, Russia

Информация о финансировании (1)

Российский фонд фундаментальных исследований

16-29-10666

In recent years, great efforts have been invested into the design of bioinspired manganese complexes, capable of conducting chemo- and stereoselective oxidations of complex organic molecules,1 such as asymmetric epoxidations, stereoselective and stereospecific C-H oxidations, oxidative desymmetrization of cyclic substrates, kinetic resolution of secondary alcohols, etc.2 In this contribution, we present an overview of the versatile catalytic reactivity of chiral bisamine-bis-pyridine manganese complexes, developed in our group and eslewhere, in a variety of asymmetric oxygenations with the environmentally benign oxidant hydrogen peroxide. Current understanding of the nature of the catalytically active, presumably high-valent manganese-oxo species, is presented.

Ottenbacher R.V. , Bryliakova A.A. , Talsi E.P. , Bryliakov K.P.
Green Stereoselective Oxidations, Catalyzed by Bioinspired bis-Amine-bis-Pyridine Manganese Complexes
В сборнике 7th Asian Conference on Coordination Chemistry.Abstract Book. 2019. – C.26.

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