Multinuclear NMR Spectroscopic Characterization of Co(III) Species- Key Intermediates of Cobalt Acetate Catalyzed Autoxidation Conference Abstracts
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Catalysis on the eve of the XXI century: science and engineering : 2nd International Memorial G.K. Boreskov Conference 07-11 Jul 1997 , Novosibirsk |
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| Source | Catalysis on the Eve of the XXI Century. Science and Engineering: II International Memorial G.K. Boreskov Conference, Novosibirsk, Russia, July 7-11, 1997: Abstracts. Part II. Poster Session Compilation, 1997. 477 c. РИНЦ |
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| Output data | Year: 1997, Article number : PPI-23, Pages count : 2 | ||||
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Funding (1)
| 1 | International Science Foundation | RBA 000 |
Abstract:
Изучена природа акт. центров ацетата кобальта(3+) в процессе окисления п-ксилола (I). Синтезированы предполагаемые интермедиаты [Co3O(OAc)6(AcOH)3]+, [Co3O(OAc)5(OH)(AcOH)3]+ и комплекс Co3+, образующийся при нагревании первых двух комплексов. В процессе окисления I показано, что последний комплекс Co3+ менее активен, чем два других комплекса.
Cite:
Babushkin D.E.
, Talsi E.P.
Multinuclear NMR Spectroscopic Characterization of Co(III) Species- Key Intermediates of Cobalt Acetate Catalyzed Autoxidation
In compilation Catalysis on the Eve of the XXI Century. Science and Engineering: II International Memorial G.K. Boreskov Conference, Novosibirsk, Russia, July 7-11, 1997: Abstracts. Part II. Poster Session. 1997. – C.55-56.
Multinuclear NMR Spectroscopic Characterization of Co(III) Species- Key Intermediates of Cobalt Acetate Catalyzed Autoxidation
In compilation Catalysis on the Eve of the XXI Century. Science and Engineering: II International Memorial G.K. Boreskov Conference, Novosibirsk, Russia, July 7-11, 1997: Abstracts. Part II. Poster Session. 1997. – C.55-56.
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