Synthesis of an Efficient Catalyst Based on Nickel and Chromium Oxides for Hydrogenation Reactions Full article
| Journal |
Kinetics and Catalysis
ISSN: 0023-1584 , E-ISSN: 1608-3210 |
||||||
|---|---|---|---|---|---|---|---|
| Output data | Year: 2010, Volume: 51, Number: 1, Pages: 135-138 Pages count : 4 DOI: 10.1134/S0023158410010222 | ||||||
| Tags | Hexavalent Chromium; Hydrogenation Selectivity; Chromium Oxide; Nickel Metal; Para Hydrogen | ||||||
| Authors |
|
||||||
| Affiliations |
|
Funding (1)
| 1 | Russian Science Support Foundation |
Abstract:
The dissolution of nickel metal in nitric acid in the presence of the dichromate anion as the oxidizer is reported. The formation of Ni(II) and Cr(III) nitrates takes place in two steps with the intermediate formation of nitrous acid. A new method to synthesize the nickel–chromium oxide catalyst from nickel and chromium nitrate solutions is suggested, in which the solutions are obtained by an environmentally friendly technology from nickel metal, chromium(VI) oxide, and nitric acid. The catalyst is highly active and selective in benzene hydrogenation and in CO preferential hydrogenation in the presence of CO2.
Cite:
Simentsova I.I.
, Minyukova T.P.
, Khassin A.A.
, Dokuchits E.
, Plyasova L.M.
, Tselyutina M.I.
, Yurieva T.M.
Synthesis of an Efficient Catalyst Based on Nickel and Chromium Oxides for Hydrogenation Reactions
Kinetics and Catalysis. 2010. V.51. N1. P.135-138. DOI: 10.1134/S0023158410010222 WOS Scopus РИНЦ ANCAN OpenAlex
Synthesis of an Efficient Catalyst Based on Nickel and Chromium Oxides for Hydrogenation Reactions
Kinetics and Catalysis. 2010. V.51. N1. P.135-138. DOI: 10.1134/S0023158410010222 WOS Scopus РИНЦ ANCAN OpenAlex
Original:
Сименцова И.И.
, Минюкова Т.П.
, Хасин А.А.
, Докучиц Е.В.
, Плясова Л.М.
, Целютина М.И.
, Юрьева Т.М.
Синтез эффективного катализатора реакций гидрирования на основе оксидов никеля и хрома
Кинетика и катализ. 2010. Т.51. №1. С.145-148. РИНЦ
Синтез эффективного катализатора реакций гидрирования на основе оксидов никеля и хрома
Кинетика и катализ. 2010. Т.51. №1. С.145-148. РИНЦ
Dates:
| Submitted: | Oct 15, 2008 |
| Published print: | Feb 1, 2010 |
| Published online: | Mar 17, 2010 |
Identifiers:
| Web of science: | WOS:000275703300022 |
| Scopus: | 2-s2.0-77952054108 |
| Elibrary: | 15336023 |
| Chemical Abstracts: | 2010:327022 |
| Chemical Abstracts (print): | 153:268005 |
| OpenAlex: | W2054181466 |