Реферат: In this work, the reaction properties of mixed silver-nickel oxide AgNiO2 were investigated in the reaction of CO oxidation ranging from room temperature up to 350 °C. X-ray photoelectron spectroscopy revealed the presence of a single oxidized silver state and the combination of Ni2+ and Ni3+ species on the surface of the as-prepared mixed oxide. It was established that AgNiO2 was able to interact with CO at room temperature. It was accompanied by the simultaneous titration of the lattice (O2--like) and weakly charged (O--like) oxygen species. The interaction with CO below 100 °C resulted in the accumulation of carbonate-like species on the AgNiO2 surface. Above 150 °C, the surface structure of mixed oxide was found to be disrupted, resulting in the formation of individual particles of metallic silver and oxidized nickel. © 2020 Author(s).

Библиографическая ссылка: Svintsitskiy D.A. , Lazarev M.K. , Kardash T.Y. , Fedorova E.A. , Slavinskaya E.M. , Boronin A.I.
Mixed Silver-Nickel Oxide AgNiO2: Probing by CO During XPS Study
Journal of Chemical Physics. 2020. V.152. N4. 044707 :1-8. DOI: 10.1063/1.5138237 WOS Scopus РИНЦ CAPlusCA PMID OpenAlex

Даты:

Поступила в редакцию:	14 нояб. 2019 г.
Принята к публикации:	1 янв. 2020 г.
Опубликована online:	22 янв. 2020 г.
Опубликована в печати:	31 янв. 2020 г.

Идентификаторы БД:

Web of science:	WOS:000519968200007
Scopus:	2-s2.0-85078481603
РИНЦ:	43237548
Chemical Abstracts:	2020:180135
Chemical Abstracts (print):	172:508440
PMID (PubMed):	32007053
OpenAlex:	W3003102817

Цитирование в БД:

БД	Цитирований
Scopus	20
Web of science	20
РИНЦ	16
OpenAlex	17

Альметрики: