Catalytic Performance and Characterization of Highly Efficient Composite Ni(Clx)/CeO2/η-Al2O3/FeCrAl Wire Mesh Catalysts for Preferential CO Methanation | Sciact - CRIS-система Института катализа

Catalytic Performance and Characterization of Highly Efficient Composite Ni(Clx)/CeO2/η-Al2O3/FeCrAl Wire Mesh Catalysts for Preferential CO Methanation Научная публикация

Журнал

ChemistrySelect
, E-ISSN: 2365-6549

Вых. Данные

Год: 2020, Том: 5, Номер: 3, Страницы: 1228-1234 Страниц : 7 DOI: 10.1002/slct.201904630

Ключевые слова

CO cleanup; FeCrAl alloy wire mesh; hydrogen-rich gas; nickel-cerium oxide catalysts; structured catalysts

Авторы

Konishcheva Margarita V. ^1,2 , Svintsitskiy Dmitry A. ^1,2 , Potemkin Dmitry I. ^1,2 , Rogozhnikov Vladimir N. ^1,2 , Sobyanin Vladimir A. ^1,2 , Snytnikov Pavel V. ^1,2

Организации

1	Boreskov Institute of Catalysis, Pr. Lavrentieva, 5, Novosibirsk, 630090, Russia
2	Novosibirsk State University, Pirogova St., 2, Novosibirsk, 630090, Russia

Информация о финансировании (1)

Федеральное агентство научных организаций России

0303-2016-0011

Structured composite Ni(Clx)/CeO2/η‐Al2O3/FeCrAl catalysts are developed for the reaction of preferential methanation of carbon monoxide in the presence of carbon dioxide. The use of a FeCrAl alloy wire mesh as a support for Ni(Cl)/CeO2 allows preparation of a heat‐conducting catalyst that is similar in performance and physical‐chemical properties to the highly efficient catalysts in the form of micro pellets, as confirmed by catalytic tests and XRD, XPS, TEM, SEM, EDX characterization techniques. Catalytic tests are carried out in hydrogen‐rich mixture which contains (vol. %): 1 CO, 65 H2, 10 H2O, 20 CO2, He – balance; weight hourly space velocity is 29,000 cm3gcat−1h−1. The structured catalyst with highly dispersed nickel and optimal chlorine content provides CO removal to a level of <10 ppm in the temperature interval of 230–300 °C. XRD, TEM, SEM and EDX analysis confirm the presence of Ni nanoparticles and CeOCl species in the catalytic coating. XPS study of samples after reductive pretreatment (simulating CO preferential methanation reaction conditions) in the preparation chamber of the spectrometer reveals the metallic state of Ni and high concentrations of Cl and Ce3+ on the catalyst surface.

Konishcheva M.V. , Svintsitskiy D.A. , Potemkin D.I. , Rogozhnikov V.N. , Sobyanin V.A. , Snytnikov P.V.
Catalytic Performance and Characterization of Highly Efficient Composite Ni(Clx)/CeO2/η-Al2O3/FeCrAl Wire Mesh Catalysts for Preferential CO Methanation
ChemistrySelect. 2020. V.5. N3. P.1228-1234. DOI: 10.1002/slct.201904630 WOS Scopus РИНЦ CAPlus OpenAlex

Поступила в редакцию:	4 дек. 2019 г.
Принята к публикации:	8 янв. 2020 г.
Опубликована online:	21 янв. 2020 г.
Опубликована в печати:	23 янв. 2020 г.

Web of science:	WOS:000508983400042
Scopus:	2-s2.0-85078106616
РИНЦ:	43237069
Chemical Abstracts:	2020:170276
OpenAlex:	W3002675846

БД	Цитирований
Scopus	10
Web of science	10
РИНЦ	9
OpenAlex	9