Photocatalytic CO2 Reduction Over Ni-Modified Cd1−xZnxS-Based Photocatalysts: Effect of Phase Composition of Photocatalyst and Reaction Media on Reduction Rate and Product Distribution Научная публикация
| Конференция |
XI International Conference Mechanisms of Catalytic Reactions 07-11 окт. 2019 , Сочи |
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| Журнал |
Topics in Catalysis
ISSN: 1022-5528 , E-ISSN: 1572-9028 |
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| Вых. Данные | Год: 2020, Том: 63, Номер: 1-2, Страницы: 121-129 Страниц : 9 DOI: 10.1007/s11244-020-01233-y | ||
| Ключевые слова | Bulk and surface modification; Cd1−xZnxS; Photocatalytic CO2 reduction; Visible light | ||
| Авторы |
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| Организации |
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Информация о финансировании (2)
| 1 | Федеральное агентство научных организаций России | 0303-2016-0016 |
| 2 | Российский фонд фундаментальных исследований | 18-03-00775 |
Реферат:
Two types of nickel-modified Cd1−xZnxS-based photocatalysts, CdxZn1−xNiySy+1 (mol% Ni = 0.05–0.5; x = 0.8) and yNiS/CdxZn1−xS (mol% Ni = 0.1–1.0; x = 0.8), were prepared via a simple two-stage technique. The samples were characterized by XRD, UV–vis spectroscopy, and XPS techniques. The activity of the synthesized photocatalysts were tested in the gas-phase photocatalytic reduction of CO2 under visible light (λ = 450 nm). It has been shown that both CdxZn1−xNiySy+1 and yNiS/CdxZn1−xS samples with ultra-low content of nickel sulfide have improved activity in the carbon dioxide reduction in comparison to bare CdxZn1−xS solid solutions. Also, it has been demonstrated that the addition of the reducing agent—hydrogen—into the system does not lead to a positive effect: the rate of CO2 reduction either remains unchanged or decreases. © 2020, Springer Science+Business Media, LLC, part of Springer Nature.
Библиографическая ссылка:
Kozlova E.A.
, Lyulyukin M.N.
, Markovskaya D.V.
, Bukhtiyarov A.V.
, Prosvirin I.P.
, Cherepanova S.V.
, Kozlov D.V.
Photocatalytic CO2 Reduction Over Ni-Modified Cd1−xZnxS-Based Photocatalysts: Effect of Phase Composition of Photocatalyst and Reaction Media on Reduction Rate and Product Distribution
Topics in Catalysis. 2020. V.63. N1-2. P.121-129. DOI: 10.1007/s11244-020-01233-y WOS Scopus РИНЦ CAPlusCA OpenAlex
Photocatalytic CO2 Reduction Over Ni-Modified Cd1−xZnxS-Based Photocatalysts: Effect of Phase Composition of Photocatalyst and Reaction Media on Reduction Rate and Product Distribution
Topics in Catalysis. 2020. V.63. N1-2. P.121-129. DOI: 10.1007/s11244-020-01233-y WOS Scopus РИНЦ CAPlusCA OpenAlex
Даты:
| Опубликована online: | 6 февр. 2020 г. |
| Опубликована в печати: | 1 мар. 2020 г. |
Идентификаторы БД:
| Web of science: | WOS:000515932300001 |
| Scopus: | 2-s2.0-85078973924 |
| РИНЦ: | 43256603 |
| Chemical Abstracts: | 2020:296824 |
| Chemical Abstracts (print): | 172:313820 |
| OpenAlex: | W3004428253 |