The Study of Reduction of Phosphomolybdovanadium Heteropoly Acids in Water Solution | Sciact - CRIS-system of Boreskov Institute of Catalysis

The Study of Reduction of Phosphomolybdovanadium Heteropoly Acids in Water Solution Full article

Journal

Russian Journal of Coordination Chemistry
ISSN: 1070-3284 , E-ISSN: 1608-3318

Output data

Year: 1976, Volume: 2, Number: 1, Pages: 55-59 Pages count : 5

Authors

Kuznetsova L.I. ¹ , Yurchenko E.N. ¹ , Maksimovskaya R.I. ¹ , Matveev K.I. ¹

Affiliations

1	Institute of Catalysis, Siberian Branch of the USSR Academy of Sciences

The composition and structure of the title heteropoly acids in solution were studied. These compounds can act as liquid phase oxidation catalysts, but the compn. must be known to establish the mechanism of their reduction. Acids containing 1-4 V atoms were reduced by N2H4 hydrate and the resulting solutions were examined by ESR and electronic spectral methods. Since the degree of reduction is ~1 e/V in the heteropoly anion, there must be a dissocn. equiliubrium producing VO2+(stepwise depending on the no. of V atoms in the anion).

Kuznetsova L.I. , Yurchenko E.N. , Maksimovskaya R.I. , Matveev K.I.
The Study of Reduction of Phosphomolybdovanadium Heteropoly Acids in Water Solution
Russian Journal of Coordination Chemistry. 1976. V.2. N1. P.55-59. РИНЦ

Кузнецова Л.И. , Юрченко Э.Н. , Максимовская Р.И. , Матвеев К.И.
Исследование восстановления фосфорномолибдованадиевых гетерополикислот в водном растворе
Координационная химия. 1976. Т.2. №1. С.67-71. РИНЦ ANCAN

Elibrary:

42311985

DB	Citing
Elibrary	2