Selective Methanation of CO in the Presence of CO2 in Hydrogen-Containing Mixtures on Nickel Catalysts Full article
| Journal |
Kinetics and Catalysis
ISSN: 0023-1584 , E-ISSN: 1608-3210 |
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| Output data | Year: 2010, Volume: 51, Number: 6, Pages: 907-913 Pages count : 7 DOI: 10.1134/S0023158410060170 | ||||||
| Tags | CARBON-MONOXIDE; METAL-CATALYSTS; MICROCHANNEL REACTOR; RICH GASES; REMOVAL; STREAM | ||||||
| Authors |
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| Affiliations |
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Funding (1)
| 1 | The Ministry of Education and Science of the Russian Federation | П185 |
Abstract:
The screening of commercial nickel catalysts for methanation and a series of nickel catalysts supported on CeO2, γ-Al2O3, and ZrO2 in the reaction of selective CO methanation in the presence of CO2 in hydrogen-containing mixtures (1.5 vol % CO, 20 vol % CO2, 10 vol % H2O, and the balance H2) was performed at the flow rate WHSV = 26000 cm3 (g Cat)−1 h−1. It was found that commercial catalytic systems like NKM-2A and NKM-4A (NIAP-07-02) were insufficiently effective for the selective removal of CO to a level of <100 ppm. The most promising catalyst is 2 wt % Ni/CeO2. This catalyst decreased the concentration of CO from 1.5 vol % to 100 ppm in the presence of 20 vol % CO2 in the temperature range of 280–360°C at a selectivity of >40%, and it retained its activity even after contact with air. The minimum outlet CO concentration of 10 ppm at 80% selectivity on a 2 wt % Ni/CeO2 catalyst was reached at a temperature of 300°C.
Cite:
Zyryanova M.M.
, Snytnikov P.V.
, Amosov Y.I.
, Venʹyaminov S.A.
, Golosman E.Z.
, Sobyanin V.A.
Selective Methanation of CO in the Presence of CO2 in Hydrogen-Containing Mixtures on Nickel Catalysts
Kinetics and Catalysis. 2010. V.51. N6. P.907-913. DOI: 10.1134/S0023158410060170 WOS Scopus РИНЦ ANCAN OpenAlex
Selective Methanation of CO in the Presence of CO2 in Hydrogen-Containing Mixtures on Nickel Catalysts
Kinetics and Catalysis. 2010. V.51. N6. P.907-913. DOI: 10.1134/S0023158410060170 WOS Scopus РИНЦ ANCAN OpenAlex
Original:
Зырянова М.М.
, Снытников П.В.
, Амосов Ю.И.
, Веньяминов С.А.
, Голосман Е.З.
, Собянин В.А.
Избирательное метанирование CO в присутствии СО2 в водородсодержащих смесях на никелевых катализаторах
Кинетика и катализ. 2010. Т.51. №6. С.938-944. РИНЦ
Избирательное метанирование CO в присутствии СО2 в водородсодержащих смесях на никелевых катализаторах
Кинетика и катализ. 2010. Т.51. №6. С.938-944. РИНЦ
Dates:
| Submitted: | Feb 2, 2010 |
| Published print: | Dec 1, 2010 |
| Published online: | Dec 16, 2010 |
Identifiers:
| Web of science: | WOS:000285363900017 |
| Scopus: | 2-s2.0-78650761783 |
| Elibrary: | 16678658 |
| Chemical Abstracts: | 2010:1565815 |
| Chemical Abstracts (print): | 154:592689 |
| OpenAlex: | W2075990793 |