Meerwein–Ponndorf–Verley–Oppenauer Non-catalytic Reaction of Monoterpenoids in Supercritical Fluids Full article
| Journal |
Russian Journal of Physical Chemistry B
ISSN: 1990-7931 , E-ISSN: 1990-7923 |
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| Output data | Year: 2019, Volume: 13, Number: 7, Pages: 1117-1120 Pages count : 4 DOI: 10.1134/S1990793119070054 | ||||
| Tags | monoterpene alcohols; monoterpene ketones; supercritical fluids; transfer hydrogenation | ||||
| Authors |
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| Affiliations |
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Funding (2)
| 1 | Federal Agency for Scientific Organizations | 0303-2016-0001 |
| 2 | Russian Foundation for Basic Research | 18-33-00659 |
Abstract:
The Meerwein–Ponndorf–Verley–Oppenauer non-catalytic reaction of cyclic monoterpenic ketones and alcohols (menthone, camphor, menthol, and borneol) was studied under supercritical conditions. It has been showed that the ketones can be reduced in supercritical isopropanol with high selectivity (89–98%) without any catalyst or base. At the same time, the conversion of menthone was 63% at 350°C, and that of camphor was 11% at 300°C for 5 h reaction. The conversions of menthol and borneol in the reverse dehydrogenation reaction in supercritical acetone were 34 and 22%, respectively, and the selectivities were 95 and 88%. Thermal dehydration is a main side reaction for all the reactions. © 2019, Pleiades Publishing, Ltd.
Cite:
Philippov A.A.
, Chibiryaev A.M.
Meerwein–Ponndorf–Verley–Oppenauer Non-catalytic Reaction of Monoterpenoids in Supercritical Fluids
Russian Journal of Physical Chemistry B. 2019. V.13. N7. P.1117-1120. DOI: 10.1134/S1990793119070054 WOS Scopus РИНЦ AN OpenAlex
Meerwein–Ponndorf–Verley–Oppenauer Non-catalytic Reaction of Monoterpenoids in Supercritical Fluids
Russian Journal of Physical Chemistry B. 2019. V.13. N7. P.1117-1120. DOI: 10.1134/S1990793119070054 WOS Scopus РИНЦ AN OpenAlex
Original:
Филиппов А.А.
, Чибиряев А.М.
Некаталитическая реакция Меервейна–Понндорфа–Верлея–Оппенауэра монотерпеноидов в сверхкритических флюидах
Сверхкритические флюиды: Теория и практика. 2018. Т.13. №3. С.77-82. RSCI РИНЦ
Некаталитическая реакция Меервейна–Понндорфа–Верлея–Оппенауэра монотерпеноидов в сверхкритических флюидах
Сверхкритические флюиды: Теория и практика. 2018. Т.13. №3. С.77-82. RSCI РИНЦ
Dates:
| Submitted: | Sep 11, 2018 |
| Accepted: | Sep 29, 2018 |
| Published print: | Dec 1, 2019 |
| Published online: | Feb 27, 2020 |
Identifiers:
| Web of science: | WOS:000519387800007 |
| Scopus: | 2-s2.0-85080123397 |
| Elibrary: | 43244620 |
| Chemical Abstracts: | 2020:448715 |
| OpenAlex: | W3008967790 |