Noncovalent Interactions in o-Fluorinated Post-Titanocene Living Ethylene Polymerization Catalyst Full article
| Journal |
Organometallics
ISSN: 0276-7333 , E-ISSN: 1520-6041 |
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| Output data | Year: 2010, Volume: 29, Number: 20, Pages: 4428-4430 Pages count : 3 DOI: 10.1021/om100729y | ||||
| Tags | METALLOCENE POLYOLEFIN CATALYSTS; F-C CONTACTS; OLEFIN POLYMERIZATION; TITANIUM COMPLEXES; ACTIVATION; METHYLALUMINOXANE; POLYETHYLENE; EQUILIBRIA; LIGANDS | ||||
| Authors |
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| Affiliations |
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Funding (2)
| 1 | Russian Foundation for Basic Research | 10-03-91330 |
| 2 | German Research Foundation | Me 1388/9-1 |
Abstract:
Multinuclear NMR spectroscopic studies of polymerization-active species generated by activation of o-F-substituted and nonsubstituted bis(enolatoimine) titanium complexes with MAO evidence a noncovalent interaction of the o-F moieties with the metal center, which is likely to facilitate living ethylene polymerization via suppression of chain transfer and of β-hydrogen transfer processes.
Cite:
Brylyakov K.P.
, Talsi E.P.
, Möller H.M.
, Baier M.C.
, Mecking S.
Noncovalent Interactions in o-Fluorinated Post-Titanocene Living Ethylene Polymerization Catalyst
Organometallics. 2010.
V.29. N20. P.4428-4430. DOI: 10.1021/om100729y
WOS
Scopus
РИНЦ
ANCAN
OpenAlex
Noncovalent Interactions in o-Fluorinated Post-Titanocene Living Ethylene Polymerization Catalyst
Organometallics. 2010.
V.29. N20. P.4428-4430. DOI: 10.1021/om100729y
WOS
Scopus
РИНЦ
ANCAN
OpenAlex
Files:
Full text from publisher
Dates:
| Submitted: | Jul 26, 2010 |
| Published online: | Sep 27, 2010 |
| Published print: | Oct 25, 2010 |
Identifiers:
| Web of science: | WOS:000282930900005 |
| Scopus: | 2-s2.0-77958087805 |
| Elibrary: | 16696308 |
| Chemical Abstracts: | 2010:1205959 |
| Chemical Abstracts (print): | 153:555283 |
| OpenAlex: | W2061090529 |