Dynamics of Propene and Propane in ZIF-8 Probed by Solid-State 2H NMR Научная публикация
Журнал |
PCCP: Physical Chemistry Chemical Physics
ISSN: 1463-9076 , E-ISSN: 1463-9084 |
||||||
---|---|---|---|---|---|---|---|
Вых. Данные | Год: 2020, Том: 22, Номер: 10, Страницы: 5976-5984 Страниц : 9 DOI: 10.1039/d0cp00270d | ||||||
Ключевые слова | METAL-ORGANIC FRAMEWORKS; ZEOLITIC IMIDAZOLATE FRAMEWORKS; LIGHT-HYDROCARBONS; SEPARATION; DIFFUSION; ADSORPTION; ETHENE/ETHANE; TEMPERATURE; MIXTURES; MOBILITY | ||||||
Авторы |
|
||||||
Организации |
|
Информация о финансировании (4)
1 | German Research Foundation | HA 1893/22-1 |
2 | Федеральное агентство научных организаций России | 0303-2016-0003 |
3 | Российский фонд фундаментальных исследований | 18-29-04009 |
4 | Российский фонд фундаментальных исследований | 18-33-00048 |
Реферат:
We present a detailed 2H NMR characterization of molecular mobility of propene and propane propagating though the microporous ZIF-8, a zeolitic imidazolate framework renowned for its outstandingly high separation selectivity for industrially relevant propene/propane mixtures. Experimental characterization of both propene and propane diffusivity in ZIF-8 has been provided. Using 2H NMR spin relaxation analysis, the motional mechanisms for propene and propane guests trapped within the ZIF-8 framework have been elucidated. Kinetic parameters for each type of motion were derived. The characteristic times for microscopic translational diffusion and activation barriers (EC3H8 = 38 kJ mol-1, EC3H6 = 13.5 kJ mol-1) for propane and propene diffusivities have been estimated. A notable difference in the observed activation barriers emphasizes that the ZIF-8 window crossing is associated with the "gate-opening" and represents an extremely shape selective process. Finally, we show that the 2H NMR technique is capable of providing reliable information on microscopic diffusivity in the ZIF-8 MOF even for molecules with slow diffusivity (<10-14 m2 s-1). This journal is © the Owner Societies.
Библиографическая ссылка:
Khudozhitkov A.E.
, Arzumanov S.S.
, Kolokolov D.I.
, Freude D.
, Stepanov A.G.
Dynamics of Propene and Propane in ZIF-8 Probed by Solid-State 2H NMR
PCCP: Physical Chemistry Chemical Physics. 2020. V.22. N10. P.5976-5984. DOI: 10.1039/d0cp00270d WOS Scopus РИНЦ CAPlusCA PMID OpenAlex
Dynamics of Propene and Propane in ZIF-8 Probed by Solid-State 2H NMR
PCCP: Physical Chemistry Chemical Physics. 2020. V.22. N10. P.5976-5984. DOI: 10.1039/d0cp00270d WOS Scopus РИНЦ CAPlusCA PMID OpenAlex
Файлы:
Полный текст от издателя
Даты:
Поступила в редакцию: | 16 янв. 2020 г. |
Принята к публикации: | 21 февр. 2020 г. |
Опубликована online: | 21 февр. 2020 г. |
Опубликована в печати: | 14 мар. 2020 г. |
Идентификаторы БД:
Web of science: | WOS:000528810000056 |
Scopus: | 2-s2.0-85081733060 |
РИНЦ: | 43251694 |
Chemical Abstracts: | 2020:348041 |
Chemical Abstracts (print): | 172:316940 |
PMID (PubMed): | 32123893 |
OpenAlex: | W3103118897 |