Luminescence of Monoclinic Y2O3:Eu Nanophosphor Produced via Laser Vaporization | Sciact - CRIS-system of Boreskov Institute of Catalysis

Luminescence of Monoclinic Y2O3:Eu Nanophosphor Produced via Laser Vaporization Full article

Journal

Optical Materials
ISSN: 0925-3467

Output data

Year: 2020, Volume: 104, Article number : 109843, Pages count : 5 DOI: 10.1016/j.optmat.2020.109843

Tags

Laser vaporization; Monoclinic Y2O3:Eu nanophosphor; Photoluminescence of Eu3+

Authors

Kostyukov A.I. ¹ , Snytnikov V.N. ^1,2 , Snytnikov Vl.N. ² , Ishchenko A.V. ^1,2 , Rakhmanova M.I. ^1,3 , Molokeev M.S. ^4,5,6 , Krylov A.S. ⁴ , Aleksandrovsky A.S. ^4,7

Affiliations

1	Novosibirsk State University, Pirogova Str. 2, 630090, Novosibirsk, Russia
2	Boreskov Institute of Catalysis SB RAS, Lavrentieva Ave. 5, 630090, Novosibirsk, Russia
3	Nikolaev Institute of Inorganic Chemistry SB RAS, Akad. Lavrentiev Ave. 3, 630090, Novosibirsk, Russia
4	Kirensky Institute of Physics Federal Research Center KSC SB RAS, Krasnoyarsk, 660036, Russia
5	Siberian Federal University, Krasnoyarsk, 660041, Russia
6	Department of Physics, Far Eastern State Transport University, Khabarovsk, 680021, Russia
7	Department of Photonics and Laser Technology, Siberian Federal University, Krasnoyarsk, 660041, Russia

Funding (1)

Russian Foundation for Basic Research

19-32-60027 (АААА-А19-119110590010-0)

Europium doped Y2O3spherical nanoparticles with the diameter ~10 nmobtained via cw laser vaporization are shown to crystallize in monoclinic symmetry class (C2/m space group). The size of nanoparticles established via HRTEM coincides with coherent scattering region established by XRD. Luminescence spectrum in the vicinity of ultranarrow transition demonstrates three peaks consistent with three inequivalent positions of Eu3+ ion in monoclinic Y2O3 lattice. Hypersensitive transition dominates in the spectrum, admitting the lack of inversion symmetry at Cs sites occupied by Eu3+. The spectrum of hypersensitive transition is expanded to the red part of spectrum due intense transitions terminating at higher-lying components of crystal-field-split 7F2 energy level. Obtaining chromaticity coordinates (0.669, 0.331)and absolute quantum yield (~21%) is possible using red phosphor based on monoclinic Y2O3:Eu3+. © 2020 Elsevier B.V.

Kostyukov A.I. , Snytnikov V.N. , Snytnikov V.N. , Ishchenko A.V. , Rakhmanova M.I. , Molokeev M.S. , Krylov A.S. , Aleksandrovsky A.S.
Luminescence of Monoclinic Y2O3:Eu Nanophosphor Produced via Laser Vaporization
Optical Materials. 2020. V.104. 109843 :1-5. DOI: 10.1016/j.optmat.2020.109843 WOS Scopus РИНЦ AN OpenAlex

Submitted:	Feb 6, 2020
Accepted:	Mar 19, 2020
Published online:	Mar 28, 2020
Published print:	Jun 1, 2020

Web of science:	WOS:000537571800006
Scopus:	2-s2.0-85082167837
Elibrary:	43255676
Chemical Abstracts:	2020:598323
OpenAlex:	W3013623959

DB	Citing
Scopus	25
Web of science	22
Elibrary	24
OpenAlex	26