1-Hexene Polymerization on a Highly Active Titanium–Magnesium Catalyst Review
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Kinetics and Catalysis
ISSN: 0023-1584 , E-ISSN: 1608-3210 |
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| Output data | Year: 2020, Volume: 61, Number: 1, Pages: 40-57 Pages count : 18 DOI: 10.1134/S002315842001005X | ||
| Tags | kinetics of polymerization; molecular-weight distribution; polyhexene; titanium–magnesium catalyst | ||
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| Affiliations |
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Abstract:
The review summarizes the results obtained by the authors in a study of the polymerization of 1‑hexene on a supported titanium–magnesium catalyst. The effects of the composition of a complex titanium–magnesium catalytic system, the composition of a reaction medium, and the conditions of polymerization on the activity of the catalyst and the molecular weight, molecular-weight distribution, and isotacticity of the resulting polyhexene were considered. The main factors (the composition of a catalytic system and the polymerization conditions) that allow one to control the catalyst activity and the molecular structure of polyhexene over wide ranges were determined. Specific features of the polymerization of 1-hexene in comparison with the polymerization of ethylene and propylene on titanium–magnesium catalysts are discussed. © 2020, Pleiades Publishing, Ltd.
Cite:
Matsko M.A.
, Echevskaya L.G.
, Zakharov V.A.
1-Hexene Polymerization on a Highly Active Titanium–Magnesium Catalyst
Kinetics and Catalysis. 2020. V.61. N1. P.40-57. DOI: 10.1134/S002315842001005X WOS Scopus РИНЦ AN OpenAlex
1-Hexene Polymerization on a Highly Active Titanium–Magnesium Catalyst
Kinetics and Catalysis. 2020. V.61. N1. P.40-57. DOI: 10.1134/S002315842001005X WOS Scopus РИНЦ AN OpenAlex
Original:
Мацько М.А.
, Ечевская Л.Г.
, Захаров В.А.
Полимеризация гексена-1 на высокоактивном титан-магниевом катализаторе
Кинетика и катализ. 2020. Т.61. №1. С.45-62. DOI: 10.31857/S0453881120010062RSCI РИНЦ OpenAlex
Полимеризация гексена-1 на высокоактивном титан-магниевом катализаторе
Кинетика и катализ. 2020. Т.61. №1. С.45-62. DOI: 10.31857/S0453881120010062RSCI РИНЦ OpenAlex
Dates:
| Submitted: | Jul 17, 2019 |
| Accepted: | Jul 31, 2019 |
| Published print: | Jan 1, 2020 |
| Published online: | Mar 29, 2020 |
Identifiers:
| Web of science: | WOS:000522168200002 |
| Scopus: | 2-s2.0-85082470549 |
| Elibrary: | 43275893 |
| Chemical Abstracts: | 2020:589903 |
| OpenAlex: | W3015047992 |