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Synthesis of Fluorine-Containing Aryl(halo)boranes from Potassium Aryl(fluoro)borates Full article

Journal Russian Journal of General Chemistry
ISSN: 1070-3632 , E-ISSN: 1608-3350
Output data Year: 2020, Volume: 90, Number: 1, Pages: 50-61 Pages count : 12 DOI: 10.1134/S1070363220010089
Tags aluminum halides; aryldihaloboranes; aryltrifluoroborates; boron halides
Authors Bardin V.V. 1 , Prikhod’ko S.A. 2 , Shmakov M.M. 2 , Shabalin A.Y. 2 , Adonin N.Y. 2
Affiliations
1 N.N. Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch of the Russian Academy of Sciences, Novosibirsk, 630090 Russia
2 Federal Research Center “G.K. Boreskov Institute of Catalysis, Siberian Branch of the Russian Academy of Sciences,” Novosibirsk, 630090 Russia

Funding (2)

1 Ministry of Science and Higher Education of the Russian Federation ГЗ-2017-2020
2 The Ministry of Education and Science of the Russian Federation

Abstract: Fluorine-containing aryldihalogenoboranes have been obtained by the reaction of boron and aluminum chlorides and bromides with potassium aryltrifluoroborates K[ArBF3] under mild conditions. In a similar way, bis(pentafluorophenyl)halogenoboranes have been synthesized by the reaction with K[(C6F5)2BF2]. The reaction of K[C6F5BF3] with AlBr3 affords a mixture of C6F5BF2 and C6F5BCl2 due to fast conversion of AlBr3 to AlBrCl2. The inductive and resonance parameters of BCl2 and BBr2 groups were calculated. © 2020, Pleiades Publishing, Ltd.
Cite: Bardin V.V. , Prikhod’ko S.A. , Shmakov M.M. , Shabalin A.Y. , Adonin N.Y.
Synthesis of Fluorine-Containing Aryl(halo)boranes from Potassium Aryl(fluoro)borates
Russian Journal of General Chemistry. 2020. V.90. N1. P.50-61. DOI: 10.1134/S1070363220010089 WOS Scopus РИНЦ AN OpenAlex
Original: Бардин В.В. , Приходько С.А. , Шмаков М.М. , Шабалин А.Ю. , Адонин Н.Ю.
Синтез фторсодержащих арил(галоген)боранов из арил(фтор)боратов калия
Журнал общей химии. 2020. Т.90. №1. С.72-84. DOI: 10.31857/S0044460X20010096RSCI РИНЦ OpenAlex
Dates:
Submitted: Jun 13, 2019
Accepted: Jun 20, 2019
Published print: Jan 1, 2020
Published online: Mar 26, 2020
Identifiers:
Web of science: WOS:000521739700008
Scopus: 2-s2.0-85082666616
Elibrary: 43263503
Chemical Abstracts: 2020:587772
OpenAlex: W3013115111
Citing:
DB Citing
Scopus 3
Web of science 4
Elibrary 4
OpenAlex 3
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