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FTIR Spectroscopy of Three Rovibrational Bands of CO Confined in Silica Aerogel: Molecule-Surface Collisions in Nanoscale Volumes Full article

Journal Chemical Physics Letters
ISSN: 0009-2614 , E-ISSN: 1873-4448
Output data Year: 2020, Volume: 749, Article number : 137451, Pages count : 4 DOI: 10.1016/j.cplett.2020.137451
Tags LINE HALF-WIDTHS; ABSORPTION
Authors Solodov A.A. 1,2 , Petrova T.M. 1 , Solodov A.M. 1 , Danilyuk A.F. 3
Affiliations
1 V.E. Zuev Institute of Atmospheric Optics SB RAS, Academician Zuev Square 1, Tomsk 634055, Russia
2 National Research Tomsk State University, pr. Lenina 36, Tomsk 634050, Russia
3 Boreskov Institute of Catalysis, pr. Lavrentieva 5, Novosibirsk 630090, Russia

Funding (1)

1 Russian Science Foundation 18-72-00145

Abstract: The absorption spectra of carbon monoxide confined in aerogel were recorded using Bruker IFS 125HR Fourier transform spectrometer within 2000–6500 cm−1 spectral range. The influence of degree of vibrational excitation on the line half-width for 1-0, 2-0 and 3-0 bands of CO confined in the same aerogel sample was studied for the first time. It was found that the character of obtained rotational dependencies is identical for all three bands and vibrational excitation insignificantly affects line HWHM. © 2020 Elsevier B.V.
Cite: Solodov A.A. , Petrova T.M. , Solodov A.M. , Danilyuk A.F.
FTIR Spectroscopy of Three Rovibrational Bands of CO Confined in Silica Aerogel: Molecule-Surface Collisions in Nanoscale Volumes
Chemical Physics Letters. 2020. V.749. 137451 :1-4. DOI: 10.1016/j.cplett.2020.137451 WOS Scopus РИНЦ AN OpenAlex
Dates:
Submitted: Feb 11, 2020
Accepted: Apr 3, 2020
Published online: Apr 6, 2020
Published print: Jun 16, 2020
Identifiers:
Web of science: WOS:000534221000004
Scopus: 2-s2.0-85082976868
Elibrary: 43272820
Chemical Abstracts: 2020:696026
OpenAlex: W3015503227
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