Real-Time Multi-Length Scale Chemical Tomography of Fixed Bed Reactors During the Oxidative Coupling of Methane Кeaction | Sciact - CRIS-system of Boreskov Institute of Catalysis

Real-Time Multi-Length Scale Chemical Tomography of Fixed Bed Reactors During the Oxidative Coupling of Methane Кeaction Full article

Journal

Journal of Catalysis
ISSN: 0021-9517 , E-ISSN: 1090-2694

Output data

Year: 2020, Volume: 386, Pages: 39-52 Pages count : 14 DOI: 10.1016/j.jcat.2020.03.027

Tags

Catalyst; Imaging; In situ; Micro; Operando; Xrd; Xrf

Authors

Vamvakeros Antonis ^1,2,3 , Matras Dorota ^2,4 , Jacques Simon D.M. ³ , di Michiel Marco ⁵ , Price Stephen W.T. ^3,6 , Senecal Pierre ^1,2 , Aran Miren Agote ^1,2 , Middelkoop Vesna ⁷ , Stenning Gavin B.G. ⁸ , Mosselmans J.Frederick W. ⁶ , Ismagilov Ilyas Z. ⁹ , Beale Andrew M. ^1,2,3

Affiliations

1	Department of Chemistry, University College London, 20 Gordon Street, London WC1H 0AJ, UK
2	Research Complex at Harwell, Harwell Science and Innovation Campus, Rutherford Appleton Laboratory, Didcot, Oxon OX11 0FA, UK
3	Finden Limited, Merchant House, 5 East St Helen Street, Abingdon OX14 5EG, UK
4	School of Materials, University of Manchester, Manchester, Lancashire M13 9PL, UK
5	ESRF- The European Synchrotron, Grenoble 38000, France
6	Diamond Light Source, Harwell Science and Innovation Campus, Didcot, Oxon OX11 0DE, UK
7	Flemish Institute for Technological Research, VITO NV, Boeretang 200, 2400 Mol, Belgium
8	ISIS Neutron and Muon Source, Rutherford Appleton Laboratory, Didcot OX11 0QX, UK
9	Boreskov Institute of Catalysis SB RAS, Pr. Akademika Lavrentieva 5, 630090 Novosibirsk, Russia

Funding (3)

1	European Commission	262840 FP7-NMP-2010-LARGE-4 DEMCAMER
2	European Commission	679933 H2020-SPIRE-2015 MEMERE
3	Engineering and Physical Sciences Research Council	EP/K007467/1

In this work, we present the results from multi-length-scale studies of a Mn-Na-W/SiO2 and a La-promoted Mn-Na-W/SiO2 catalyst during the oxidative coupling of methane reaction. The catalysts were investigated from the reactor level (mm scale) down to the single catalyst particle level (μm scale) with different synchrotron X-ray chemical computed tomography techniques (multi-modal chemical CT experiments). These operando spatially-resolved studies performed with XRD-CT (catalytic reactor) and multi-modal μ-XRF/XRD/absorption CT (single catalyst particle) revealed the multiple roles of the La promoter and how it provides the enhancement in catalyst performance. It is also shown that non-crystalline Mn species are part of the active catalyst component rather than crystalline Mn2O3/Mn7SiO12 or MnWO4. © 2020 Elsevier Inc.

Vamvakeros A. , Matras D. , Jacques S.D.M. , di Michiel M. , Price S.W.T. , Senecal P. , Aran M.A. , Middelkoop V. , Stenning G.B.G. , Mosselmans J.F.W. , Ismagilov I.Z. , Beale A.M.
Real-Time Multi-Length Scale Chemical Tomography of Fixed Bed Reactors During the Oxidative Coupling of Methane Кeaction

Journal of Catalysis. 2020. V.386. P.39-52. DOI: 10.1016/j.jcat.2020.03.027 WOS Scopus РИНЦ AN OpenAlex

Full text from publisher

Submitted:	Nov 27, 2019
Accepted:	Mar 24, 2020
Published online:	Apr 18, 2020
Published print:	Jun 1, 2020

Web of science:	WOS:000533629300005
Scopus:	2-s2.0-85083324078
Elibrary:	43275203
Chemical Abstracts:	2020:750305
OpenAlex:	W3016510239

DB	Citing
Scopus	38
Web of science	32
Elibrary	29
OpenAlex	44