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Study of Bifunctional Hydrocracking and Hydroisodeparaffinization Catalysts Based on Zeolites and Alumophosphates, Part 2: Effect of the Activity of Hydrogenating and Acidic Components on the Activity and Selectivity of Hydroisodeparaffinization Catalysts Научная публикация

Журнал Catalysis in Industry
ISSN: 2070-0504 , E-ISSN: 2070-0555
Вых. Данные Год: 2020, Том: 12, Номер: 1, Страницы: 81-87 Страниц : 7 DOI: 10.1134/S2070050420010067
Ключевые слова acidic and hydro–dehydrogenating components; acidic support; bifunctional catalyst; hydroisodeparaffinization catalyst; palladium; SAPO-11 and SAPO-31 silicoalumophosphates
Авторы Echevskii G.V. 1 , Weixin Qui 1,2 , Kodenev E.G. 1 , Toktarev A.V. 1 , Chunmei Du 1,2
Организации
1 Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences, Novosibirsk, 630090 Russia
2 Sino-Russian Institute, Novosibirsk State University, Novosibirsk, 630090 Russia

Информация о финансировании (1)

1 Федеральное агентство научных организаций России 0303-2016-0010

Реферат: Two different series of bifunctional hydroisodeparaffinization catalysts with deposited palladium and based on SAPO-11 and SAPO-31 are fabricated and studied, with (1) varied activity of the acidic component at a constant activity of the hydro–dehydrogenating component and (2) varied activity of the hydro–dehydrogenating component at a constant activity of the acidic component. It is shown that the temperature of 90% n-decane conversion on the catalysts with the same hydro–dehydrogenating activity depends linearly on the overall activity of the acidic catalyst component. The character of this dependence is identical for both structural types of SAPO-11 and SAPO-31 silicoalumophosphates. The bifunctional catalysts based on SAPO-31 are much more active than those based on SAPO-11. At the same overall activity of the acidic component, the temperature of 90% n-decane conversion on the Pd/SAPO-31 catalysts is 50°C lower than on the Pd/SAPO-11 catalysts. Ways of controlling the overall activity and selectivity of a hydroisodeparaffinization catalyst by varying the activity of the acidic and/or hydro–dehydrogenating component of a bifunctional catalyst are shown. An increase in the hydro–dehydrogenating activity of the catalyst enhances the hydroisomerizing activity of a bifunctional catalyst with virtually no changes in selectivity toward isomers. An increase in the overall activity of the acidic component also enhances the hydroisomerizing activity of a bifunctional catalyst, but appreciably alters its selectivity toward isomers. © 2020, Pleiades Publishing, Ltd.
Библиографическая ссылка: Echevskii G.V. , Weixin Q. , Kodenev E.G. , Toktarev A.V. , Chunmei D.
Study of Bifunctional Hydrocracking and Hydroisodeparaffinization Catalysts Based on Zeolites and Alumophosphates, Part 2: Effect of the Activity of Hydrogenating and Acidic Components on the Activity and Selectivity of Hydroisodeparaffinization Catalysts
Catalysis in Industry. 2020. V.12. N1. P.81-87. DOI: 10.1134/S2070050420010067 WOS Scopus РИНЦ OpenAlex
Оригинальная: Ечевский Г.В. , Вэйсинь Ц. , Коденев Е.Г. , Токтарев А.В. , Чуньмэй Д.
Исследование бифункциональных катализаторов гидрокрекинга и гидроизодепарафинизации на основе цеолитов и алюмофосфатов Часть 2. Влияние активности гидрирующего и кислотного компонентов на активность и селективность катализаторов гидроизодепарафинизации
Катализ в промышленности. 2019. Т.19. №3. С.240-246. DOI: 10.18412/1816-0387-2019-3-240-246RSCI РИНЦ CAPlus OpenAlex
Даты:
Поступила в редакцию: 28 февр. 2019 г.
Принята к публикации: 16 апр. 2019 г.
Опубликована в печати: 1 янв. 2020 г.
Опубликована online: 9 апр. 2020 г.
Идентификаторы БД:
Web of science: WOS:000525620800010
Scopus: 2-s2.0-85083253666
РИНЦ: 43271454
OpenAlex: W3015603831
Цитирование в БД:
БД Цитирований
Scopus 3
Web of science 3
РИНЦ 3
OpenAlex 3
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