Effect of Sulfosalicylic Acid Treatment on the Properties of Beta Zeolite and Performance of NiW/Beta-Based Catalysts in Hexadecane Hydrocracking Full article
| Journal |
Applied Catalysis A: General
ISSN: 0926-860X , E-ISSN: 1873-3875 |
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| Output data | Year: 2020, Volume: 598, Article number : 117573, Pages count : 10 DOI: 10.1016/j.apcata.2020.117573 | ||
| Tags | BEA zeolite; Sulfosalicylic; Acid; Acid sites; Hexadecane hydrocracking | ||
| Authors |
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| Affiliations |
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Funding (1)
| 1 | Ministry of Science and Higher Education of the Russian Federation | ГЗ-2017-2020 |
Abstract:
Effect of sulfosalicylic acid treatment on the properties of Beta zeolite (BEA and BEA-SA) and performance of NiW/Beta-Al2O3 catalysts in hexadecane hydrocracking have been studied. The acid treatment had almost no effect on porous structure of Beta zeolite while it resulted in significant changes in acidity. The decrease in concentration of Brønsted (35 to 25 μmol/g) and Lewis acid sites (119 to 54 μmol/g) was observed that could be related to the removal of extra framework aluminum. NiW/BEA-Al2O3 catalyst having zeolite with higher acidity demonstrated higher activity in hexadecane hydrocracking. The hexadecane conversion was 54.5–95.6% and 32.4–93.9% for NiW/BEA-Al2O3 and NiW/BEA-SA-Al2O3, respectively. However, NiW/BEA-SA-Al2O3 demonstrated higher selectivity to target products (C5-C15 hydrocarbons and iso-C16) than NiW/BEA-Al2O3 (63.8 and 14.4 % vs. 62.4 and 4.5 %, respectively) at similar hexadecane conversion of ∼95 %. This can be attributed mainly to the effect of sulfosalicylic acid treatment on Beta zeolite acidity.
Cite:
Bukhtiyarova M.V.
, Toktarev A.V.
, Kazakov M.O.
, Kodenev E.G.
, Pereyma V.Y.
, Gabrienko A.A.
, Bukhtiyarov A.V.
, Echevsky G.V.
Effect of Sulfosalicylic Acid Treatment on the Properties of Beta Zeolite and Performance of NiW/Beta-Based Catalysts in Hexadecane Hydrocracking
Applied Catalysis A: General. 2020. V.598. 117573 :1-10. DOI: 10.1016/j.apcata.2020.117573 WOS Scopus РИНЦ AN OpenAlex
Effect of Sulfosalicylic Acid Treatment on the Properties of Beta Zeolite and Performance of NiW/Beta-Based Catalysts in Hexadecane Hydrocracking
Applied Catalysis A: General. 2020. V.598. 117573 :1-10. DOI: 10.1016/j.apcata.2020.117573 WOS Scopus РИНЦ AN OpenAlex
Dates:
| Submitted: | Jan 16, 2020 |
| Accepted: | Apr 15, 2020 |
| Published online: | Apr 21, 2020 |
| Published print: | May 25, 2020 |
Identifiers:
| Web of science: | WOS:000536133800021 |
| Scopus: | 2-s2.0-85083560484 |
| Elibrary: | 43297801 |
| Chemical Abstracts: | 2020:825373 |
| OpenAlex: | W3018037691 |