Fabrication of the Functionalized Carbon Nanomaterials via Catalytic Pyrolysis of Heteroatom-Containing Compounds | Sciact - CRIS-система Института катализа

Fabrication of the Functionalized Carbon Nanomaterials via Catalytic Pyrolysis of Heteroatom-Containing Compounds Научная публикация

Конференция

The 8th International Conference on Material Science and Engineering Technology & The 6th International Conference on Chemical and Material Engineering
19-21 окт. 2019 , Singapore

Журнал

Materials Science Forum
ISSN: 0255-5476 , E-ISSN: 1662-9752

Вых. Данные

Год: 2020, Том: 998, Страницы: 157-162 Страниц : 6 DOI: 10.4028/www.scientific.net/MSF.998.157

Ключевые слова

Catalytic Chemical Vapor Deposition, Closed Reactor System, Functionalization of the Carbon Nanomaterials, Nickel-Based Alloys, Self-Organized Catalysts

Авторы

Vedyagin Aleksey A. ¹ , Mishakov Ilya V. ^1,2 , Bauman Yury I. ¹ , Kenzhin Roman M. ¹

Организации

1	Boreskov Institute of Catalysis SB RAS
2	Novosibirsk State University

Информация о финансировании (2)

1	Федеральное агентство научных организаций России	0303-2016-0014
2	Российский фонд фундаментальных исследований	18-29-19053

Commercial Ni-Cr and specially prepared Ni-Pd alloys were used as a catalyst’s precursor for the synthesis of the heteroatom-doped carbon nanofibers. In order to provide the intercalation of the doping heteroatom into the structure of the carbon product, the synthesis was performed in the one pot regime, when heteroatom-containing substance was subjected to decomposition simultaneously with carbon source compound. Chlorobenzene, 1-bromobutane, 1-iodobutane, and melamine were used as heteroatom-and carbon-containing sources in the experiments carried out in a closed reactor system. 1,2-dichloriethane, being a source of chlorine and carbon, was decomposed in a flow-through reactor system. Additionally, acetonitrile and carbon dioxide were admixed to 1,2-dichloriethane as nitrogen and oxygen sources. It was found that in all the cases, except for halogenated butanes, the amount of the intercalated heteroatom can reach 3-8 at.%. Both the substrate’s nature and the composition of the reaction mixture were found to affect the morphologic features of the carbon nanostructures produced.

Vedyagin A.A. , Mishakov I.V. , Bauman Y.I. , Kenzhin R.M.
Fabrication of the Functionalized Carbon Nanomaterials via Catalytic Pyrolysis of Heteroatom-Containing Compounds
Materials Science Forum. 2020. V.998. P.157-162. DOI: 10.4028/www.scientific.net/MSF.998.157 Scopus РИНЦ OpenAlex

Поступила в редакцию:	22 окт. 2019 г.
Принята к публикации:	30 окт. 2019 г.
Опубликована online:	23 июн. 2020 г.

Scopus:	2-s2.0-85088302823
РИНЦ:	45424174
OpenAlex:	W3036451766

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