Bi-Component Redox Systems Obtained from Iridium or Rhodium Chlorides and Molybdophosphoric Heteropoly Acid Full article
| Journal |
Reaction Kinetics, Mechanisms and Catalysis
ISSN: 1878-5190 , E-ISSN: 1878-5204 |
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| Output data | Year: 2010, Volume: 101, Number: 1, Pages: 1-12 Pages count : 12 DOI: 10.1007/s11144-010-0204-0 | ||
| Tags | Benzene, Catalysis, Ir(III) and Rh(III) complexes, Molybdophosphoric heteropoly acid, Oxidation | ||
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| Affiliations |
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Abstract:
An XP, IR and UV–VIS spectroscopy study was carried out to characterize the compositions of molybdophosphate heteropoly anions with Ir(III) or Rh(III) hydroxo–chloro complexes, such as Ir1.1Cl2.4O x H y ·(PMo12O40)·16.0 H2O, where x is the number of oxygen atoms in the coordination sphere of iridium, and also mixed-valent species containing partially reduced and dehydrated heteropoly acid of suggested composition (Ir0, IrIII) n Cl m O x H y (PMo 12−p VIMo p VO40−p/2) (on the average, n ≈ 1, m < 1, p ≥ 4). The mixed-valent Ir containing species showed stable activity in the gas-phase oxidation of benzene by O2–H2 mixture.
Cite:
Kuznetsova L.I.
, Koscheev S.V.
, Kuznetsova N.I.
, Detusheva L.G.
Bi-Component Redox Systems Obtained from Iridium or Rhodium Chlorides and Molybdophosphoric Heteropoly Acid
Reaction Kinetics, Mechanisms and Catalysis. 2010. V.101. N1. P.1-12. DOI: 10.1007/s11144-010-0204-0 WOS Scopus РИНЦ ANCAN OpenAlex
Bi-Component Redox Systems Obtained from Iridium or Rhodium Chlorides and Molybdophosphoric Heteropoly Acid
Reaction Kinetics, Mechanisms and Catalysis. 2010. V.101. N1. P.1-12. DOI: 10.1007/s11144-010-0204-0 WOS Scopus РИНЦ ANCAN OpenAlex
Dates:
| Submitted: | Feb 19, 2010 |
| Accepted: | May 11, 2010 |
| Published online: | Jun 4, 2010 |
| Published print: | Oct 1, 2010 |
Identifiers:
| Web of science: | WOS:000281111500001 |
| Scopus: | 2-s2.0-77952856689 |
| Elibrary: | 18089981 |
| Chemical Abstracts: | 2010:1050934 |
| Chemical Abstracts (print): | 155:96552 |
| OpenAlex: | W2003805178 |