Sciact
  • EN
  • RU

Bi-Component Redox Systems Obtained from Iridium or Rhodium Chlorides and Molybdophosphoric Heteropoly Acid Full article

Journal Reaction Kinetics, Mechanisms and Catalysis
ISSN: 1878-5190 , E-ISSN: 1878-5204
Output data Year: 2010, Volume: 101, Number: 1, Pages: 1-12 Pages count : 12 DOI: 10.1007/s11144-010-0204-0
Tags Benzene, Catalysis, Ir(III) and Rh(III) complexes, Molybdophosphoric heteropoly acid, Oxidation
Authors Kuznetsova Lidia I. 1 , Koscheev Sergei V. 1 , Kuznetsova Nina I. 1 , Detusheva Ludmila G. 1
Affiliations
1 Boreskov Institute of Catalysis SB RAS

Abstract: An XP, IR and UV–VIS spectroscopy study was carried out to characterize the compositions of molybdophosphate heteropoly anions with Ir(III) or Rh(III) hydroxo–chloro complexes, such as Ir1.1Cl2.4O x H y ·(PMo12O40)·16.0 H2O, where x is the number of oxygen atoms in the coordination sphere of iridium, and also mixed-valent species containing partially reduced and dehydrated heteropoly acid of suggested composition (Ir0, IrIII) n Cl m O x H y (PMo 12−p VIMo p VO40−p/2) (on the average, n ≈ 1, m < 1, p ≥ 4). The mixed-valent Ir containing species showed stable activity in the gas-phase oxidation of benzene by O2–H2 mixture.
Cite: Kuznetsova L.I. , Koscheev S.V. , Kuznetsova N.I. , Detusheva L.G.
Bi-Component Redox Systems Obtained from Iridium or Rhodium Chlorides and Molybdophosphoric Heteropoly Acid
Reaction Kinetics, Mechanisms and Catalysis. 2010. V.101. N1. P.1-12. DOI: 10.1007/s11144-010-0204-0 WOS Scopus РИНЦ ANCAN OpenAlex
Dates:
Submitted: Feb 19, 2010
Accepted: May 11, 2010
Published online: Jun 4, 2010
Published print: Oct 1, 2010
Identifiers:
Web of science: WOS:000281111500001
Scopus: 2-s2.0-77952856689
Elibrary: 18089981
Chemical Abstracts: 2010:1050934
Chemical Abstracts (print): 155:96552
OpenAlex: W2003805178
Citing:
DB Citing
Web of science 1
Elibrary 1
OpenAlex 1
Altmetrics: