Abstract: Activity and selectivity of supported Ni, Pt, and Pd catalysts were studied in the liquidphase reductive amination of cyclohexanone at temperatures ranging from 100 to 150 °C. The catalyst 20% Ni/SiO2 is most active and selective providing a maximum yield of cyclohexylamine. The influence of the reaction conditions on the parameters of the catalytic process was studied. A detailed analysis of the reaction products was carried out using 13C NMR spectroscopy and gas chromatography coupled with mass spectrometry (GC-MS). This made it possible to refine the reaction mechanism and to identify a new by-product earlier unknown in the literature.

Cite: Ivanov D.P. , Dubkov K.A. , Babushkin D.E. , Pirutko L.V. , Semikolenov S.V.
Liquid-Phase Hydroamination of Cyclohexanone
Russian Chemical Bulletin. 2010. V.59. N10. P.1896-1901. DOI: 10.1007/s11172-010-0330-x WOS Scopus РИНЦ ANCAN OpenAlex

Original: Иванов Д.П. , Дубков К.А. , Бабушкин Д.Э. , Пирютко Л.В. , Семиколенов С.В.
Жидкофазное гидроаминирование циклогексанона
Известия Академии наук. Серия химическая. 2010. №10. С.1846-1851. РИНЦ

Dates:

Submitted:	Dec 11, 2009
Published print:	Oct 1, 2010
Published online:	Mar 13, 2011

Identifiers:

Web of science:	WOS:000288257800006
Scopus:	2-s2.0-79956058303
Elibrary:	16978073
Chemical Abstracts:	2011:306752
Chemical Abstracts (print):	154:312854
OpenAlex:	W2014860445

Citing:

DB	Citing
Web of science	2
Scopus	2
Elibrary	2
OpenAlex	7

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