Transformation of a Proton Insulator to a Conductor via Reversible Amorphous to Crystalline Structure Transformation of MOFs | Sciact - CRIS-system of Boreskov Institute of Catalysis

Transformation of a Proton Insulator to a Conductor via Reversible Amorphous to Crystalline Structure Transformation of MOFs Full article

Journal

Chemical Communications
ISSN: 1359-7345 , E-ISSN: 1364-548X

Output data

Year: 2020, Volume: 56, Number: 32, Pages: 4468-4471 Pages count : 4 DOI: 10.1039/d0cc00755b

Tags

COORDINATION; MAGNESIUM

Authors

Song Yoodae ^1,2 , Khudozhitkov Alexander E. ^3,4 , Lee Jihyun ² , Kang Hyosik ² , Kolokolov Daniil I. ^3,4 , Stepanov Alexander G. ^3,4 , Yoon Minyoung Yoon ¹

Affiliations

1	Department of Chemistry, Kyungpook National University, Daegu 41566, Republic of Korea
2	Department of Nanochemistry, Gachon University, Seongnam 13420, Republic of Korea
3	Boreskov Institute of Catalysis, Siberian Branch of Russian Academy of Science, Novosibirsk 630090, Russia
4	Novosibirsk State University, Novosibirsk 630090, Russia

Funding (4)

1	Federal Agency for Scientific Organizations	0303-2016-0003
2	Russian Foundation for Basic Research	18-503-51023
3	National Research Foundation of Korea	NRF-2014R1A1A2A16049980
4	National Research Foundation of Korea	NRF-2017K 2A9A1A06050536

In this study, a successful proton conduction modulation of MOFs, from an ionic insulator to an ionic conductor, is demonstrated through their structural transformation. It is shown that the reversible structural change from amorphous to crystalline phases allows for the reversible proton conduction modulation of MOFs. Moreover, the proton conduction mechanism of the ionic conductor phase is elucidated by 2H NMR analysis. This journal is © The Royal Society of Chemistry.

Song Y. , Khudozhitkov A.E. , Lee J. , Kang H. , Kolokolov D.I. , Stepanov A.G. , Yoon M.Y.
Transformation of a Proton Insulator to a Conductor via Reversible Amorphous to Crystalline Structure Transformation of MOFs
Chemical Communications. 2020. V.56. N32. P.4468-4471. DOI: 10.1039/d0cc00755b WOS Scopus РИНЦ AN OpenAlex

Submitted:	Jan 29, 2020
Accepted:	Mar 6, 2020
Published online:	Mar 9, 2020
Published print:	Apr 25, 2020

Web of science:	WOS:000529215100016
Scopus:	2-s2.0-85083912966
Elibrary:	43274607
Chemical Abstracts:	2020:465898
OpenAlex:	W3010533597

DB	Citing
Scopus	11
Web of science	10
Elibrary	11
OpenAlex	11