Synthesis, Characterization, and Biological Activity of Co(II), Ni(II), and Cu(II) Complexes Derived from N,N'-bis(2-N-Tozylaminobenzylidene)Diaminodipropyliminate Ligand | Sciact - CRIS-system of Boreskov Institute of Catalysis

Synthesis, Characterization, and Biological Activity of Co(II), Ni(II), and Cu(II) Complexes Derived from N,N'-bis(2-N-Tozylaminobenzylidene)Diaminodipropyliminate Ligand Full article

Journal

Inorganica Chimica Acta
ISSN: 0020-1693 , E-ISSN: 1873-3255

Output data

Year: 2020, Volume: 510, Article number : 119766, Pages count : 9 DOI: 10.1016/j.ica.2020.119766

Tags

metal-chelates, Schiff base, X-ray crystal structures, X-ray absorption spectroscopy, TD-DFT, biological activity

Authors

Vlasenko Valery G. ¹ , Burlov Anatolii S. ² , Koshchienko Yurii V. ² , Kiskin Mikhail A. ³ , Garnovskii Dmitrii A. ⁴ , Zubavichus Yan V. ⁵ , Kolodina Alexandra A. ² , Trigub Alexander L. ⁶ , Zubenko Alexander A. ⁷ , Drobin Yurii D. ⁷

Affiliations

1	Southern Federal University, Institute of Physics
2	Southern Federal University, Institute of Physical and Organic Chemistry
3	Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences
4	Southern Scientific Centre of Russian Academy of Sciences
5	Siberian Branch of the Russian Academy of Sciences, Boreskov Institute of Catalysis
6	National Research Center «Kurchatov Institute»
7	North-Caucasian Zonal Scientific Research Veterinary Institute – Branch of the Federal State Budget Scientific Institution “Federal Rostov Agricultural Research Centre”,

Funding (1)

Ministry of Science and Higher Education of the Russian Federation

ИнГр/2020-01-ИФ

A series of novel complexes of Co(II), Ni(II), and Cu(II) based on pentadentate Schiff base 4-methyl-N-[2-[(E)-3-[3-[(E)-[2-(p-tolylsulfonylamino)phenyl]methyleneamino]propyl amino]propyliminomethyl]phenyl]benzenesulfonamide were synthesized by chemical and electrochemical methods. All compounds have been fully characterized by C, H, N elemental analysis, FT-IR, 1H NMR, UV-vis, and magnetochemical techniques. The local atomic structures of complexes were determined from analysis of EXAFS and XANES of Co, Ni, and Cu K-edges. The crystal and molecular structures of complexes were determined by the X-ray diffraction method. The nature of the bands of electronic absorption spectra of the complexes in CH2Cl2 solutions were interpreted using the results of quantum chemical calculations in the TD-DFT approximation. The antibacterial, protistocidal, and fungistatic activities of the H2L and its Co(II), Ni(II), and Cu(II) complexes have been screened against Penicillium italicum, Colpoda steinii, Escherichia coli 078 and Staphylococcus aureus P-209, and the results were compared with the activities of furazolidone, toltrazuril, and benomyl.

Vlasenko V.G. , Burlov A.S. , Koshchienko Y.V. , Kiskin M.A. , Garnovskii D.A. , Zubavichus Y.V. , Kolodina A.A. , Trigub A.L. , Zubenko A.A. , Drobin Y.D.
Synthesis, Characterization, and Biological Activity of Co(II), Ni(II), and Cu(II) Complexes Derived from N,N'-bis(2-N-Tozylaminobenzylidene)Diaminodipropyliminate Ligand
Inorganica Chimica Acta. 2020. V.510. 119766 :1-9. DOI: 10.1016/j.ica.2020.119766 WOS Scopus РИНЦ AN OpenAlex

Submitted:	Apr 22, 2020
Accepted:	May 14, 2020
Published online:	May 16, 2020
Published print:	Sep 24, 2020

Web of science:	WOS:000541377100023
Scopus:	2-s2.0-85085215947
Elibrary:	43272133
Chemical Abstracts:	2020:1000876
OpenAlex:	W3025894110

DB	Citing
Scopus	12
Web of science	12
Elibrary	17
OpenAlex	12