Superprotonic Conductivity in Metal-Organic Framework via Solvent-Free Coordinative Urea Insertion Full article
| Journal |
Journal of the American Chemical Society
ISSN: 0002-7863 , E-ISSN: 1520-5126 |
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| Output data | Year: 2020, Volume: 142, Number: 15, Pages: 6861-6865 Pages count : 5 DOI: 10.1021/jacs.0c00303 | ||||||
| Tags | SINGLE-CRYSTAL; PROTON; CHEMISTRY | ||||||
| Authors |
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| Affiliations |
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Funding (3)
| 1 | Russian Foundation for Basic Research | 20-33-70141 |
| 2 | Federal Agency for Scientific Organizations | 0303-2016-0003 |
| 3 | Japan Science and Technology Agency | JPMJAC1501 |
Abstract:
Highly stable superprotonic conductivity (>10-2 S cm-1) has been achieved through the unprecedented solvent-free-coordinative urea insertion in MOF-74 [M2(dobdc), M = Ni2+, Mg2+ dobdc = 2,5-dioxido-1,4-benzenedicarboxylate] without an acidic moiety. The urea is bound to open metal sites and alters the void volume and surface functionality, which triggers a significant change in proton conductivity and diffusion mechanism. Solid-state 2H NMR revealed that the high conductivity was attributed to the strengthening of the hydrogen bonds between guest H2O induced by hydrogen bonds in the interface between H2O and the polarized coordinated urea. Copyright © 2020 American Chemical Society.
Cite:
Sarango-Ramírez M.K.
, Lim D-W.
, Kolokolov D.I.
, Khudozhitkov A.E.
, Stepanov A.G.
, Kitagawa H.
Superprotonic Conductivity in Metal-Organic Framework via Solvent-Free Coordinative Urea Insertion
Journal of the American Chemical Society. 2020. V.142. N15. P.6861-6865. DOI: 10.1021/jacs.0c00303 WOS Scopus РИНЦ OpenAlex AN PMID
Superprotonic Conductivity in Metal-Organic Framework via Solvent-Free Coordinative Urea Insertion
Journal of the American Chemical Society. 2020. V.142. N15. P.6861-6865. DOI: 10.1021/jacs.0c00303 WOS Scopus РИНЦ OpenAlex AN PMID
Dates:
| Submitted: | Jan 16, 2020 |
| Published online: | Mar 12, 2020 |
| Published print: | Apr 15, 2020 |
Identifiers:
| ≡ Web of science: | WOS:000526300600006 |
| ≡ Scopus: | 2-s2.0-85084507487 |
| ≡ Elibrary: | 43268439 |
| ≡ OpenAlex: | W3012304918 |
| ≡ Chemical Abstracts: | 2020:491396 |
| ≡ PMID: | 32163272 |