γ-Hydroxypropylation of 2,6-Dialkyl(aryl)phenols with Allyl Alcohol and Its Derivatives | Sciact - CRIS-system of Boreskov Institute of Catalysis

γ-Hydroxypropylation of 2,6-Dialkyl(aryl)phenols with Allyl Alcohol and Its Derivatives Full article

Journal

Russian Journal of General Chemistry
ISSN: 1070-3632 , E-ISSN: 1608-3350

Output data

Year: 2010, Volume: 80, Number: 11, Pages: 2290-2297 Pages count : 8 DOI: 10.1134/S1070363210110101

Tags

General Chemistry; Methyl Acrylate; Reaction Mass; Allyl Alcohol; Butylphenol

Authors

Krysin A.P. ¹ , Khalikova N.U. ¹ , Khlebnikova T.B. ² , Nogina N.I. ¹ , Mamatyuk V.I. ¹

Affiliations

1	Vorozhtsov Novosibirsk Institute of Organic Chemistry, Siberian Branch, Russian Academy of Sciences
2	Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences

The composition of the products of the reaction of 2,6-disubstituted phenols with allyl alcohol and its derivatives in an alkaline medium was investigated, the conditions for carrying out the reaction with the predominant formation of 4-(3-hydroxypropyl)-2,6-dialkyl(aryl)phenols were found, and its mechanism was suggested. The reaction was examined on an industrial scale. An important result is the practical demonstration of alkaline catalysis performed under homogeneous conditions with participation of phenols, when the used alkaline catalyst is recovered in the process without the formation of waste waters.

Krysin A.P. , Khalikova N.U. , Khlebnikova T.B. , Nogina N.I. , Mamatyuk V.I.
γ-Hydroxypropylation of 2,6-Dialkyl(aryl)phenols with Allyl Alcohol and Its Derivatives
Russian Journal of General Chemistry. 2010. V.80. N11. P.2290-2297. DOI: 10.1134/S1070363210110101 WOS Scopus РИНЦ ANCAN OpenAlex

Крысин А.П. , Халикова Н.У. , Хлебникова Т.Б. , Ногина Н.И. , Маматюк В.И.
Гамма-гидроксипропилирование 2, 6-диалкил (арил) фенолов аллиловым спиртом и его производными
Журнал общей химии. 2010. Т.80. №11. С.1826-1833. РИНЦ

Submitted:	Jan 21, 2010
Published print:	Nov 1, 2010
Published online:	Dec 25, 2010

Web of science:	WOS:000286663100010
Scopus:	2-s2.0-79251474970
Elibrary:	16713822
Chemical Abstracts:	2010:1623221
Chemical Abstracts (print):	154:258923
OpenAlex:	W2033994958

Пока нет цитирований