Effect of the Preparation Procedure on the Structural Peculiarities and Catalytic Properties of Pt/(CeO2-TiO2) Catalyst in CO Oxidation Full article
| Conference |
10th International Symposium on the Scientific Bases for the Preparation of Heterogeneous Catalysts 11-15 Jul 2010 , Louvain-la-Neuve |
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| Source | Scientific Bases for the Preparation of Heterogeneous Catalysts : Proceedings of the 10th International Symposium, Louvain-la-Neuve, Belgium, July 11-15, 2010 Compilation, Elsevier. Amsterdam, The Netherlands.2010. 857 c. ISBN 9780444536013. |
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| Journal |
Studies in Surface Science and Catalysis
ISSN: 0167-2991 |
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| Output data | Year: 2010, Volume: 175, Pages: 369-372 Pages count : 4 DOI: 10.1016/S0167-2991(10)75062-X | ||||
| Tags | Microstructure, Oxidation of CO | ||||
| Authors |
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| Affiliations |
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Funding (2)
| 1 | The Ministry of Education and Science of the Russian Federation | 2.1.1/729 |
| 2 | The Ministry of Education and Science of the Russian Federation | П252/23.07.2009 |
Abstract:
The procedure of the Pt/(CeO2–TiO2) catalyst preparation is crucial for the microstructure and catalytic properties in CO oxidation. Impregnation of ceria doped TiO2 with platinum nitrate solution followed heating in air at 500 °C leads to the formation of ultra fine platinum particles 0.5-0.6 nm in size stabilized at interblock boundaries of the support formed by irregularly intergrown anatase particles. Calcination of the catalyst in hydrogen at 250 °C leads to the formation of the platinum particles with 2–5 nm in size. The catalyst containing ultra fine platinum particles is much more active than the catalyst with particles of 2-5 nm in size. Infrared spectra of CO adsorbed on Pt revealed that high CO oxidation activity is exhibited by ultra fine Pt particles due to the high concentration of weakly bonded Pt0-CO complexes.
Cite:
Shutilov A.A.
, Zenkovets G.A.
Effect of the Preparation Procedure on the Structural Peculiarities and Catalytic Properties of Pt/(CeO2-TiO2) Catalyst in CO Oxidation
In compilation Scientific Bases for the Preparation of Heterogeneous Catalysts : Proceedings of the 10th International Symposium, Louvain-la-Neuve, Belgium, July 11-15, 2010. – Elsevier., 2010. – C.369-372. – ISBN 9780444536013. DOI: 10.1016/S0167-2991(10)75062-X WOS Scopus РИНЦ ANCAN OpenAlex
Effect of the Preparation Procedure on the Structural Peculiarities and Catalytic Properties of Pt/(CeO2-TiO2) Catalyst in CO Oxidation
In compilation Scientific Bases for the Preparation of Heterogeneous Catalysts : Proceedings of the 10th International Symposium, Louvain-la-Neuve, Belgium, July 11-15, 2010. – Elsevier., 2010. – C.369-372. – ISBN 9780444536013. DOI: 10.1016/S0167-2991(10)75062-X WOS Scopus РИНЦ ANCAN OpenAlex
Dates:
| Published print: | Jan 1, 2010 |
| Published online: | Jul 8, 2010 |
Identifiers:
| Web of science: | WOS:000291935400062 |
| Scopus: | 2-s2.0-78649336577 |
| Elibrary: | 16677020 |
| Chemical Abstracts: | 2010:1318453 |
| Chemical Abstracts (print): | 154:290929 |
| OpenAlex: | W97029417 |