Methods for Selective Benzylic C–H Oxofunctionalization of Organic Compounds Обзор
| Журнал |
Russian Chemical Reviews
ISSN: 0036-021X , E-ISSN: 1468-4837 |
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| Вых. Данные | Год: 2020, Том: 89, Номер: 6, Страницы: 587-628 Страниц : 42 DOI: 10.1070/rcr4918 | ||||
| Ключевые слова | TERT-BUTYL HYDROPEROXIDE; IRON-CATALYZED OXIDATION; 2-ARYLACETIC ACID-DERIVATIVES; LIGHT PHOTOREDOX CATALYSIS; AQUEOUS HYDROGEN-PEROXIDE; O-IODOXYBENZOIC ACID; AEROBIC OXIDATION; TRANSITION-METAL; NONHEME IRON; CARBONYL-COMPOUNDS | ||||
| Авторы |
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| Организации |
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Информация о финансировании (1)
| 1 | Федеральное агентство научных организаций России | 0303-2016-0005 |
Реферат:
The development of methods for the selective oxidation of C–H groups of organic compounds resulting in C–O bond formation is a challenging problem in modern synthetic organic chemistry. Versatile methods for the oxofunctionalization of these groups are currently lacking. Approaches for the oxidation of benzylic C–H groups having a relatively weak C–H bond (the homolytic bond dissociation energy is ~80–90
kcal mol−1) differ from the methods used for the oxidation of aliphatic and aromatic C–H groups with stronger C–H bonds. The review summarizes homogeneous catalytic and non-catalytic methods for the selective oxofunctionalization of benzylic groups of organic compounds developed in the past 40 years. Reactions using various oxidizing agents in the presence or in the absence of transition metal compounds are considered. Putative mechanisms of selected transformations are discussed. Particular focus is placed on the selective oxidation of various substrates.
Библиографическая ссылка:
Lubov D.P.
, Talsi E.P.
, Bryliakov K.P.
Methods for Selective Benzylic C–H Oxofunctionalization of Organic Compounds
Russian Chemical Reviews. 2020. V.89. N6. P.587-628. DOI: 10.1070/rcr4918 WOS Scopus РИНЦ OpenAlex CAPlus
Methods for Selective Benzylic C–H Oxofunctionalization of Organic Compounds
Russian Chemical Reviews. 2020. V.89. N6. P.587-628. DOI: 10.1070/rcr4918 WOS Scopus РИНЦ OpenAlex CAPlus
Оригинальная:
Лубов Д.П.
, Талзи Е.П.
, Брыляков К.П.
Методы селективной бензильной C–H-оксофункционализации органических соединений
Успехи химии. 2020. Т.89. №6. С.587-628. DOI: 10.1070/RCR4918?locatt=label:RUSSIAN РИНЦ
Методы селективной бензильной C–H-оксофункционализации органических соединений
Успехи химии. 2020. Т.89. №6. С.587-628. DOI: 10.1070/RCR4918?locatt=label:RUSSIAN РИНЦ
Даты:
| Поступила в редакцию: | 10 авг. 2019 г. |
| Опубликована online: | 1 июн. 2020 г. |
| Опубликована в печати: | 30 июн. 2020 г. |
Идентификаторы БД:
| ≡ Web of science: | WOS:000537861800001 |
| ≡ Scopus: | 2-s2.0-85086674069 |
| ≡ РИНЦ: | 43301738 |
| ≡ OpenAlex: | W2983285047 |
| ≡ Chemical Abstracts: | 2020:1613540 |