Catalyzed Transfer Hydrogenation by 2-propanol for Highly Selective PAHs Reduction Full article
| Journal |
Catalysis Today
ISSN: 0920-5861 , E-ISSN: 1873-4308 |
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| Output data | Year: 2021, Volume: 379, Pages: 15-22 Pages count : 8 DOI: 10.1016/j.cattod.2020.06.060 | ||
| Tags | Polyaromatic hydrocarbons; 2-Propanol; Raney® nickel; Transfer hydrogenation; Hydrogenative dearomatization | ||
| Authors |
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| Affiliations |
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Funding (2)
| 1 | Ministry of Science and Higher Education of the Russian Federation | 075-15-2019-1876 |
| 2 | Russian Foundation for Basic Research | 18-29-06022 |
Abstract:
Catalytic hydrogenation of mono-, di- and trinuclear aromatic compounds has been studied under hydrogen transfer conditions at 150 °C and 82 °C in 2-PrOH as a hydrogen donor and with Raney® nickel as a catalyst. In contrast to conjugated or condensed aromatic rings, isolated ones demonstrated low reactivity in transfer hydrogenation (TH) that can be used to increase the hydrogenation selectivity of the reaction. So, naphthalene and biphenyl are partially hydrogenated into tetralin and cyclohexylbenzene, respectively, with excellent conversion (≥ 96%) and selectivity (≥ 98%) for 5–6 h at 82 °C. Increasing the reaction temperature to 150 °C results expectedly in the hydrogenation of second aromatic ring, which occurs slowly enough. Only 8% of decaline and 42% of dicyclohexyl, correspondingly, were obtained after 5 h at 150 °C. At the same time, TH of trinuclear anthracene and phenanthrene at 150 °C resulted in the formation of deeper hydrogenated octahydro-anthracenes and -phenanthrenes, respectively.
Cite:
Philippov A.A.
, Chibiryaev A.M.
, Martyanov O.N.
Catalyzed Transfer Hydrogenation by 2-propanol for Highly Selective PAHs Reduction
Catalysis Today. 2021. V.379. P.15-22. DOI: 10.1016/j.cattod.2020.06.060 WOS Scopus РИНЦ OpenAlex AN
Catalyzed Transfer Hydrogenation by 2-propanol for Highly Selective PAHs Reduction
Catalysis Today. 2021. V.379. P.15-22. DOI: 10.1016/j.cattod.2020.06.060 WOS Scopus РИНЦ OpenAlex AN
Dates:
| Submitted: | Oct 30, 2019 |
| Accepted: | Jun 23, 2020 |
| Published online: | Jun 30, 2020 |
| Published print: | Nov 1, 2021 |
Identifiers:
| ≡ Web of science: | WOS:000686897100003 |
| ≡ Scopus: | 2-s2.0-85087773275 |
| ≡ Elibrary: | 45481357 |
| ≡ OpenAlex: | W3037248221 |
| ≡ Chemical Abstracts: | 2020:1391050 |