Silica, Alumina and Ceria Supported Au–Cu Nanoparticles Prepared via the Decomposition of [Au(en)2]2[Cu(C2O4)2]3·8H2O Single-Source Precursor: Synthesis, Characterization and Catalytic performance in CO PROX | Sciact - CRIS-system of Boreskov Institute of Catalysis

Silica, Alumina and Ceria Supported Au–Cu Nanoparticles Prepared via the Decomposition of [Au(en)2]2[Cu(C2O4)2]3·8H2O Single-Source Precursor: Synthesis, Characterization and Catalytic performance in CO PROX Full article

Journal

Catalysis Today
ISSN: 0920-5861 , E-ISSN: 1873-4308

Output data

Year: 2014, Volume: 235, Pages: 103-111 Pages count : 9 DOI: 10.1016/j.cattod.2014.04.026

Tags

Alloy nanoparticles, Au-Cu catalysts, Bimetallic nanoparticles, Double complex salts, Gold-copper catalysts, Preferential CO oxidation

Authors

Potemkin D.I. ^1,2 , Semitut E.Yu. ^2,3 , Shubin Yu.V. ^2,3 , Plyusnin P.E. ^2,3 , Snytnikov P.V. ^1,2 , Makotchenko E.V. ^2,3 , Osadchii D.Yu. ^1,2 , Svintsitskiy D.A. ^1,2 , Venyaminov S.A. ¹ , Korenev S.V. ^2,3 , Sobyanin V.A. ^1,2

Affiliations

1	Boreskov Institute of Catalysis, Pr. Lavrentieva, 5, Novosibirsk 630090, Russia
2	Novosibirsk State University, Pirogova Street, 2, Novosibirsk 630090, Russia
3	Nikolaev Institute of Inorganic Chemistry, Pr. Lavrentieva, 3, Novosibirsk 630090, Russia

Funding (6)

1	Russian Foundation for Basic Research	14-03-00411
2	Russian Foundation for Basic Research	14-03-00457
3	Siberian Branch of the Russian Academy of Sciences	124
4	The Ministry of Education and Science of the Russian Federation	16.740.11.0473
5	Council for Grants of the President of the Russian Federation	МК-2737.2013.3
6	Council for Grants of the President of the Russian Federation	СП-857.2012.1

Silica, alumina and ceria supported bimetallic Au–Cu catalysts were prepared via the decomposition of [Au(en)2]2[Cu(C2O4)2]3·8H2O double complex salt inside the support pore structure. XRD and TEM analyses indicated the selective formation of supported Au0.4Cu0.6 alloy nanoparticles with preset stoichiometry on the support surface. Catalysts were tested in CO preferential oxidation (PROX) reaction. Au0.4Cu0.6/CeO2 catalyst showed best characteristics having higher CO consumption at higher selectivity in the realistic hydrogen-rich mixture containing CO2 and H2O, compared with Au/CeO2 catalyst.

Potemkin D.I. , Semitut E.Y. , Shubin Y.V. , Plyusnin P.E. , Snytnikov P.V. , Makotchenko E.V. , Osadchii D.Y. , Svintsitskiy D.A. , Venyaminov S.A. , Korenev S.V. , Sobyanin V.A.
Silica, Alumina and Ceria Supported Au–Cu Nanoparticles Prepared via the Decomposition of [Au(en)2]2[Cu(C2O4)2]3·8H2O Single-Source Precursor: Synthesis, Characterization and Catalytic performance in CO PROX
Catalysis Today. 2014. V.235. P.103-111. DOI: 10.1016/j.cattod.2014.04.026 WOS Scopus РИНЦ ANCAN OpenAlex

Submitted:	Nov 16, 2013
Accepted:	Apr 15, 2014
Published online:	Jun 3, 2014
Published print:	Oct 15, 2014

Web of science:	WOS:000340946200013
Scopus:	2-s2.0-84905667325
Elibrary:	23979273
Chemical Abstracts:	2014:978884
Chemical Abstracts (print):	161:363716
OpenAlex:	W2058337700

DB	Citing
Web of science	33
Scopus	34
Elibrary	34
OpenAlex	37