Factors Affecting the Catalytic Performance of Zr,Al-Pillared Clays in the Synthesis of Propylene Glycol Methyl Ether | Sciact - CRIS-system of Boreskov Institute of Catalysis

Factors Affecting the Catalytic Performance of Zr,Al-Pillared Clays in the Synthesis of Propylene Glycol Methyl Ether Full article

Journal

Industrial and Engineering Chemistry Research
ISSN: 0888-5885 , E-ISSN: 1520-5045

Output data

Year: 2014, Volume: 53, Number: 35, Pages: 13565-13574 Pages count : 10 DOI: 10.1021/ie501048a

Tags

Aluminum; Aromatic compounds; Catalyst activity; Chlorine compounds; Fourier transform infrared spectroscopy; Gallium; Nuclear magnetic resonance spectroscopy; Propylene; X ray diffraction

Authors

Timofeeva M.N. ^1,2 , Panchenko V.N. ¹ , Matrosova M.M. ¹ , Andreev A.S. ¹ , Tsybulya S.V. ¹ , Gil A. ³ , Vicente M.A. ⁴

Affiliations

1	Boreskov Institute of Catalysis, Prospect Akademika Lavrentieva 5, 630090 Novosibirsk, Russia
2	Novosibirsk State Technical University, Prospect Karl Marksa 20, 630092 Novosibirsk, Russia
3	Department of Applied Chemistry, Public University of Navarra, 31006 Pamplona, Spain
4	Department of Inorganic Chemistry, University of Salamanca, Salamanca, Spain

Funding (1)

Federal Agency for Scientific Organizations

V.44.2.12.

Series of Al-, Ga-, and Zr,Al-pillared clays (Al-MM, Ga-MM, and Zr,Al-MM) were prepared through the intercalation of Al-, Ga-, and Zr-polyoxocations into three layered aluminosilicates with various textural properties and chemical compositions. Zr,Al-phases with the structure of bayerite–boehmite were also synthesized using Al and Zr oligomeric solutions, prepared from aluminum chloride and zirconium oxychloride, respectively, as metal sources, with Zr/Al ratios of 0–0.143. All materials were characterized by X-ray diffraction; elemental analysis; DR-UV–vis, FTIR, and 27Al MAS NMR spectroscopies; and N2 adsorption/desorption analysis. FTIR spectroscopy using pyridine, benzonitrile, and deuterated chloroform as probe molecules was used to investigate the acid–base properties of the solids. The catalytic performance of these materials was investigated in the synthesis of 1-methoxy-2-propanol from methanol and propylene oxide. It was found that the catalytic properties of Zr,Al-pillared clays depended on the textural properties (pore diameter), chemical composition (Si/Al molar ratio and Zr content), and type of Al salt (nitrate or chloride) used as the Al source for the preparation of the pillaring solution. The type of metal cation in the polyoxocations affected the reaction rate and isomer selectivity. Al-MM was found to exhibit a higher catalytic efficiency than Ga-MM and Zr-MM.

Timofeeva M.N. , Panchenko V.N. , Matrosova M.M. , Andreev A.S. , Tsybulya S.V. , Gil A. , Vicente M.A.
Factors Affecting the Catalytic Performance of Zr,Al-Pillared Clays in the Synthesis of Propylene Glycol Methyl Ether
Industrial and Engineering Chemistry Research. 2014. V.53. N35. P.13565-13574. DOI: 10.1021/ie501048a WOS Scopus РИНЦ ANCAN OpenAlex

Submitted:	Mar 12, 2014
Accepted:	Jul 19, 2014
Published online:	Aug 21, 2014
Published print:	Sep 3, 2014

Web of science:	WOS:000341227200002
Scopus:	2-s2.0-84906879120
Elibrary:	23987583
Chemical Abstracts:	2014:1184155
Chemical Abstracts (print):	161:391661
OpenAlex:	W2318722992

DB	Citing
Web of science	24
Scopus	24
Elibrary	24
OpenAlex	26