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Hydrous TiO2 Materials and Their Application for Sorption of Inorganic Ions Научная публикация

Журнал Chemical Engineering Journal
ISSN: 1385-8947 , E-ISSN: 1873-3212
Вых. Данные Год: 2014, Том: 251, Страницы: 131-137 Страниц : 7 DOI: 10.1016/j.cej.2014.04.058
Ключевые слова Amorphous, Flow adsorption, Inorganic ions, Mesoporous materials, Static adsorption, Water purification
Авторы Tsydenov Dmitry E. 1 , Shutilov Alexey A. 1 , Zenkovets Galina A. 1 , Vorontsov Alexander V. 1
Организации
1 Boreskov Institute of Catalysis, Pr. Ak. Lavrentyeva 5, Novosibirsk 630090, Russian Federation

Информация о финансировании (2)

1 Российский фонд фундаментальных исследований 13-08-01286
2 Президиум РАН 27.56

Реферат: The work is devoted to preparation of hydrous TiO2 adsorbent samples, their characterization, determination of adsorption isotherm types for Zn(II) and Pb(II), choosing the best adsorbent sample and measurement of its capability to purify flow of water from As(V), Bi(III), Cd(II), Co(II), Cr(VI), Pb(II), Th(IV), U(VI), V(V) and Zn(II). 10 adsorbent samples were synthesized by hydrolysis of TiOSO4 and TiCl4 in aqueous ammoniac, the highest surface area being 620 m2/g. Adsorption over TiO2 of Zn(II) follows Sips isotherm whereas that of Pb(II) follows Freundlich isotherm, both isotherms converge into Freundlich isotherm at low concentrations. Using Pb(II) adsorption, the best TiO2 adsorbent was chosen that has adsorption capacity 293 mg/g at concentration equal to maximum allowable concentration (MAC). This adsorbent purifies water from Co(II), Zn(II), Pb(II), U(VI), Th(IV) and Cd(II) during single pass through column to below MAC. Purification from Cr(VI), V(V), Bi(III) and As(V) required preliminary washing the adsorbent with HNO3 solution.
Библиографическая ссылка: Tsydenov D.E. , Shutilov A.A. , Zenkovets G.A. , Vorontsov A.V.
Hydrous TiO2 Materials and Their Application for Sorption of Inorganic Ions
Chemical Engineering Journal. 2014. V.251. P.131-137. DOI: 10.1016/j.cej.2014.04.058 WOS Scopus РИНЦ CAPlusCA OpenAlex
Даты:
Поступила в редакцию: 3 мар. 2014 г.
Принята к публикации: 12 апр. 2014 г.
Опубликована online: 24 апр. 2014 г.
Опубликована в печати: 1 сент. 2014 г.
Идентификаторы БД:
Web of science: WOS:000338802500016
Scopus: 2-s2.0-84900322050
РИНЦ: 21877470
Chemical Abstracts: 2014:982483
Chemical Abstracts (print): 161:114971
OpenAlex: W1970030595
Цитирование в БД:
БД Цитирований
Web of science 28
Scopus 27
РИНЦ 26
OpenAlex 27
Альметрики: