Three-Stage Heavy Oil Hydroprocessing over Hierarchically Porous Catalysts: Effect of Macroporous Structure | Sciact - CRIS-system of Boreskov Institute of Catalysis

Three-Stage Heavy Oil Hydroprocessing over Hierarchically Porous Catalysts: Effect of Macroporous Structure Conference Abstracts

Conference

EuropaCat-XIII: 13th European Congress on Catalysis
27-31 Aug 2017 , Florence

Source

13th European Congress on Catalysis
Compilation, 2017.

Output data

Year: 2017, Article number : SS7.9, Pages count : 2

Authors

Semeykina V.S. ^1,2 , Polukhin A.V. ¹ , Lysikov A.I. ^1,2 , Parkhomchuk E.V. ^1,2

Affiliations

1	Boreskov Institute of Catalysis, Novosibirsk, 630090, Russian Federation
2	Novosibirsk State University, Novosibirsk, 630090, Russian Federation

The present work is devoted to the effect of hierarchical macro-mesoporous structure on catalyst activity and stability in heavy oil hydroprocessing. A facile “hard” template method has been applied to the preparation of materials with narrow bimodal pore size distribution, high macropore volume, sufficient specific surface area and mechanical strength. The catalysts have been tested in the consecutive three-stage hydroprocessing of heavy Tatar oil: I stage – metal and asphaltene removal over a “guard-type” catalyst Al2O3 , II stage – S removal over a hydrotreating NiMoS/Al2O3 catalyst, III stage – hydrocracking and isomerization over NiMoS/Al2O3-ZSM-5 catalyst modified with zeolite as an acidic additive. Developed hierarchical texture is found to greatly improve the catalyst stability against metal and asphaltene deposition, as well as to increase hydrocracking activity of NiMoS/Al2O3 catalysts, especially those modified with zeolite as an acidic additive.

Semeykina V.S. , Polukhin A.V. , Lysikov A.I. , Parkhomchuk E.V.
Three-Stage Heavy Oil Hydroprocessing over Hierarchically Porous Catalysts: Effect of Macroporous Structure
In compilation 13th European Congress on Catalysis. 2017. – C.321-322.

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