One-Pot Terpene Alcohols Amination Towards Biologically Active Compounds Synthesis | Sciact - CRIS-system of Boreskov Institute of Catalysis

One-Pot Terpene Alcohols Amination Towards Biologically Active Compounds Synthesis Conference Abstracts

Conference

EuropaCat-XIII: 13th European Congress on Catalysis
27-31 Aug 2017 , Florence

Source

13th European Congress on Catalysis
Compilation, 2017.

Output data

Year: 2017, Article number : 2D.5, Pages count : 2

Authors

Demidova Yu.S. ^1,2 , Simakova I.L. ^1,2 , Suslov E.V. ³ , Beloshapkin S. ⁴ , Volcho K.P. ^2,3 , Salakhutdinov N.F. ^2,3 , Simakov A.V. ⁵ , Murzin D.Yu. ⁶

Affiliations

1	Boreskov Institute of Catalysis, Novosibirsk, 630090, Russia
2	Novosibirsk State University, Novosibirsk, 630090, Russia
3	Novosibirsk Institute of Organic Chemistry, Novosibirsk, 630090, Russia
4	Materials & Surface Science Institute, University of Limerick, Limerick, V94 T9PX, Ireland
5	Centro de Nanociencias y Nanotecnología, UNAM, Ensenada, 22860, México
6	Åbo Akademi University, Turku/Åbo, FI-20500, Finland

Funding (1)

Russian Foundation for Basic Research

16-33-60028

One-pot myrtenol amination was studied in the presence of nanosized gold catalysts supported on different metal oxides with equimolar amounts of the substrates in the temperature range 413-453 K under nitrogen pressure. The products distribution and conversion were found to depend strongly on support nature, catalyst redox activation and active metal component composition. The reaction kinetics was modeled based on the mechanistic considerations with the catalyst deactivation step introduced into the mechanism. The effect of the substrate structure was explored. Introduction of hydrogen donors was shown to be efficient for controlled hydrogenation of the C=N bond preserving the C=C bond without addition of external molecular hydrogen resulting in the enhanced yield of the desired amine.

Demidova Y.S. , Simakova I.L. , Suslov E.V. , Beloshapkin S. , Volcho K.P. , Salakhutdinov N.F. , Simakov A.V. , Murzin D.Y.
One-Pot Terpene Alcohols Amination Towards Biologically Active Compounds Synthesis
In compilation 13th European Congress on Catalysis. 2017. – C.40-41.

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