Metal–Organic Frameworks of the MIL-101 Family as Heterogeneous Single-Site Catalysts | Sciact - CRIS-system of Boreskov Institute of Catalysis

Metal–Organic Frameworks of the MIL-101 Family as Heterogeneous Single-Site Catalysts Review

Journal

Proceedings of the Royal Society A: Mathematical, Physical & Engineering Sciences
ISSN: 1364-5021 , E-ISSN: 1471-2946

Output data

Year: 2012, Volume: 468, Number: 2143, Pages: 2017-2034 Pages count : 18 DOI: 10.1098/rspa.2012.0072

Tags

Allylic oxidation, Carboxylation, Cyclohexane, Metal-organic frameworks, MIL-101, Single-site heterogeneous catalysts

Authors

Maksimchuk Nataliya V. ¹ , Zalomaeva Olga V. ¹ , Skobelev Igor Y. ¹ , Kovalenko Konstantin A. ^2,3 , Fedin Vladimir P. ^2,3 , Kholdeeva Oxana A. ¹

Affiliations

1	Boreskov Institute of Catalysis, pr. Lavrentieva 5, Novosibirsk 630090, Russia
2	Nikolaev Institute of Inorganic Chemistry, pr. Lavrentieva 3, Novosibirsk 630090, Russia
3	Department of Inorganic Chemistry, Novosibirsk State University, Pirogova str. 2, Novosibirsk, 630090, Russia

Funding (2)

1	Russian Foundation for Basic Research	09-03-12112
2	Russian Foundation for Basic Research	09-03-93109

In this short review paper, we survey our recent findings in the catalytic applications of mesoporous metal–organic frameworks of the MIL-101 family (Fe- and Cr-MIL-101) and demonstrate their potential in two types of liquid-phase processes: (i) selective oxidation of hydrocarbons with green oxidants—O2 and tert-butyl hydroperoxide—and (ii) coupling reaction of organic oxides with CO2. A comparison with conventional single-site catalysts is made with special attention to issues of the catalyst’s resistance to metal leaching and the nature of catalysis.

Maksimchuk N.V. , Zalomaeva O.V. , Skobelev I.Y. , Kovalenko K.A. , Fedin V.P. , Kholdeeva O.A.
Metal–Organic Frameworks of the MIL-101 Family as Heterogeneous Single-Site Catalysts

Proceedings of the Royal Society A: Mathematical, Physical & Engineering Sciences. 2012. V.468. N2143. P.2017-2034. DOI: 10.1098/rspa.2012.0072 WOS Scopus РИНЦ ANCAN OpenAlex

Full text from publisher

Submitted:	Dec 30, 2011
Accepted:	Feb 14, 2012
Published online:	Mar 14, 2012
Published print:	Jul 8, 2012

Web of science:	WOS:000304451200012
Scopus:	2-s2.0-84862215157
Elibrary:	17991349
Chemical Abstracts:	2012:1084342
Chemical Abstracts (print):	157:307092
OpenAlex:	W2132562173

DB	Citing
Web of science	94
Scopus	98
Elibrary	86
OpenAlex	100