Flow Hydrogenation of 5-acetoxymethylfurfural over Cu-Based Catalysts Full article
| Journal |
Molecular Catalysis
ISSN: 2468-8231 |
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| Output data | Year: 2020, Volume: 494, Article number : 111132, Pages count : 6 DOI: 10.1016/j.mcat.2020.111132 | ||
| Tags | 5-Acetoxymethylfurfural; Selective hydrogenation; Cu-based catalyst; Layered double hydroxide; Flow reactor | ||
| Authors |
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| Affiliations |
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Funding (2)
| 1 | Federal Agency for Scientific Organizations | 0303-2016-0004 |
| 2 | Federal Agency for Scientific Organizations | 0303-2016-0006 (V.44.1.6) |
Abstract:
5-Acetoxymethylfurfural (AMF) is a promising starting material for synthesis of the valuable furan derivatives. The catalytic properties of Cu-based catalysts obtained from layered double hydroxides were studied in flow hydrogenation of AMF to 5-(acetoxymethyl)-2-furanmethanol (AMFM) in the present work. The resulting product can be easily converted to 2,5-bis(hydroxymethyl)furan which has significant potential in the production of polymers and pharmaceuticals. It was found that hydrogenation of AMF gives AMFM with selectivity of 98 % at the full conversion of the substrate under mild reaction conditions (90°C and 10 bar). The influence of the solvent nature, Cu/Al ratio and calcination temperature on the catalyst performance was investigated.
Cite:
Nuzhdin A.L.
, Bukhtiyarova M.V.
, Bulavchenko O.A.
, Bukhtiyarova G.A.
Flow Hydrogenation of 5-acetoxymethylfurfural over Cu-Based Catalysts
Molecular Catalysis. 2020. V.494. 111132 :1-6. DOI: 10.1016/j.mcat.2020.111132 WOS Scopus РИНЦ AN OpenAlex
Flow Hydrogenation of 5-acetoxymethylfurfural over Cu-Based Catalysts
Molecular Catalysis. 2020. V.494. 111132 :1-6. DOI: 10.1016/j.mcat.2020.111132 WOS Scopus РИНЦ AN OpenAlex
Dates:
| Submitted: | May 13, 2020 |
| Accepted: | Jul 20, 2020 |
| Published online: | Jul 28, 2020 |
| Published print: | Oct 1, 2020 |
Identifiers:
| Web of science: | WOS:000566542700001 |
| Scopus: | 2-s2.0-85088637033 |
| Elibrary: | 45409020 |
| Chemical Abstracts: | 2020:1480742 |
| OpenAlex: | W3045544451 |